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Gold-Catalyzed Reactions of Enynals with Alkenes for Synthesis Binaphthyl Derivatives.
Hao, Jun-Jie; Wu, Juan; Jiang, Tao; Luo, Hejiang; Li, Rong-Tao.
Affiliation
  • Hao JJ; Faculty of Life Science and Technology, Kunming University of Science and Technology, Kunming, 650500, P. R. China.
  • Wu J; Faculty of Life Science and Technology, Kunming University of Science and Technology, Kunming, 650500, P. R. China.
  • Jiang T; Faculty of Life Science and Technology, Kunming University of Science and Technology, Kunming, 650500, P. R. China.
  • Luo H; Faculty of Life Science and Technology, Kunming University of Science and Technology, Kunming, 650500, P. R. China.
  • Li RT; Faculty of Life Science and Technology, Kunming University of Science and Technology, Kunming, 650500, P. R. China.
J Org Chem ; 89(9): 6074-6084, 2024 May 03.
Article in En | MEDLINE | ID: mdl-38626391
ABSTRACT
A PPh3Au[B(C6F5)4]-catalyzed reaction of enynals and alkenes for the construction of binaphthyl derivatives was described. This transformation was achieved through o-Quinodimethane (o-QDM) intermediate's extended conjugated addition process. The reaction has the advantages of wide substrate scopes, mild reaction conditions, high efficiency, and good scalability.
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2024 Type: Article
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Full text: 1 Collection: 01-internacional Database: MEDLINE Language: En Journal: J Org Chem Year: 2024 Type: Article