Photoredox-Catalysis Fluorosulfonyldifluoromethylation of Unactivated Alkenes and (Hetero)arenes with ICF2SO2F.
Org Lett
; 26(32): 6900-6904, 2024 Aug 16.
Article
in En
| MEDLINE
| ID: mdl-39115249
ABSTRACT
The fluorosulfonyldifluoromethylation of unactivated alkenes and (hetero)arenes with iododifluoromethanesulfonyl fluoride (ICF2SO2F) under visible light photoredox catalysis was successfully developed. Key to the successful fluorosulfonyldifluoromethylation of aromatic compounds was the usage of AgOTf as an additive to promote the formation of the CF2SO2F radical. The protocol provided a straightforward way to introduce the interesting and useful CF2SO2F group on sp3 and sp2 carbons.
Full text:
1
Collection:
01-internacional
Database:
MEDLINE
Language:
En
Journal:
Org Lett
Journal subject:
BIOQUIMICA
Year:
2024
Type:
Article
Affiliation country:
China