(Mu-oxalato-O1,O2:O1',O2')bis[aqua(diethylenetriamine)nickel(II)] bis(hexafluorophosphate) dihydrate.
Acta Crystallogr C
; 58(Pt 2): m81-3, 2002 Feb.
Article
en En
| MEDLINE
| ID: mdl-11828087
ABSTRACT
The title compound, [Ni(2)(C(2)O(4))(C(4)H(13)N(3))(2)(H(2)O)(2)](PF(6))(2).2H(2)O, contains a dinuclear oxalato-bridged nickel(II) complex cation. The structure determination reveals the presence of a centrosymmetric binuclear complex where the oxalate ligand is coordinated in a bis-bidentate mode to the Ni atoms. The distorted octahedral environment of each Ni atom is completed by the three N atoms of the diethylenetriamine ligand in a fac arrangement and by one O atom from a water molecule. PF(6)(-) acts as counter-anion. A two-dimensional network of hydrogen bonds links the cations and anions and stabilizes the structure.
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Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Acta Crystallogr C
Año:
2002
Tipo del documento:
Article
País de afiliación:
España