Asymmetric synthesis of cyclo-archaeol and ß-glucosyl cyclo-archaeol.

Ferrer, Catalina; Fodran, Peter; Barroso, Santiago; Gibson, Robert; Hopmans, Ellen C; Damsté, Jaap Sinninghe; Schouten, Stefan; Minnaard, Adriaan J

Ferrer, Catalina; Fodran, Peter; Barroso, Santiago; Gibson, Robert; Hopmans, Ellen C; Damsté, Jaap Sinninghe; Schouten, Stefan; Minnaard, Adriaan J.

Afiliación

Ferrer C; Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 7, 9747 AG Groningen, The Netherlands.

Org Biomol Chem ; 11(15): 2482-92, 2013 Apr 21.

Article en En | MEDLINE | ID: mdl-23440078

ABSTRACT

ABSTRACT

An efficient asymmetric synthesis of cyclo-archaeol and ß-glucosyl cyclo-archaeol is presented employing catalytic asymmetric conjugate addition and catalytic epoxide ring opening as the key steps. Their occurrence in deep sea hydrothermal vents has been confirmed by chromatographic comparison with natural samples.

Asunto(s)

Archaea/química; Glicerofosfolípidos/química; Glicerofosfolípidos/síntesis química; Catálisis; Técnicas de Química Sintética

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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Archaea / Glicerofosfolípidos Idioma: En Revista: Org Biomol Chem Asunto de la revista: BIOQUIMICA / QUIMICA Año: 2013 Tipo del documento: Article País de afiliación: Países Bajos

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