Gold(I)-catalysed one-pot synthesis of chromans using allylic alcohols and phenols.

Coutant, Eloi; Young, Paul C; Barker, Graeme; Lee, Ai-Lan

Coutant, Eloi; Young, Paul C; Barker, Graeme; Lee, Ai-Lan.

Afiliación

Coutant E; Institute of Chemical Sciences, Heriot-Watt University, Edinburgh, EH14 1LP, United Kingdom.

Beilstein J Org Chem ; 9: 1797-806, 2013.

Article en En | MEDLINE | ID: mdl-24062845

ABSTRACT

ABSTRACT

A gold(I)-catalysed reaction of allylic alcohols and phenols produces chromans regioselectively via a one-pot Friedel-Crafts allylation/intramolecular hydroalkoxylation sequence. The reaction is mild, practical and tolerant of a wide variety of substituents on the phenol.

Palabras clave

FriedelCrafts; allylic alcohols; chromans; gold catalysis; heterocycles

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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Beilstein J Org Chem Año: 2013 Tipo del documento: Article País de afiliación: Reino Unido

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