(Diacetoxyiodo)benzene-Mediated Reaction of Ethynylcarbinols: Entry to α,α'-Diacetoxy Ketones and Glycerol Derivatives.
J Org Chem
; 80(12): 6496-501, 2015 Jun 19.
Article
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| MEDLINE
| ID: mdl-26011401
ABSTRACT
Efficient access to α,α'-diacetoxy ketones has been developed from ethynylcarbinols and PhI(OAc)2. A plausible mechanism for this was proposed on the basis of experimental studies. The usefulness of α,α'-diacetoxy ketone products has been documented, and glycerol derivatives can be easily synthesized in good yields via a one-pot reaction.
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01-internacional
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MEDLINE
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En
Revista:
J Org Chem
Año:
2015
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Article