Synthesis of Benzyltributylstannanes by the Reaction of N-Tosylhydrazones with Bu3SnH.
J Org Chem
; 82(1): 624-632, 2017 01 06.
Article
en En
| MEDLINE
| ID: mdl-27966352
ABSTRACT
An efficient stannylation process with N-tosylhydrazones or directly with carbonyl compounds has been developed. A series of functionalized benzyl- and alkyltributylstannanes can be synthesized in moderate to good yields under transition-metal-free conditions. Tandem transformations involving stannylation/Stille cross-coupling reaction have been carried out without purification of the benzyltributylstannane intermediates to afford a series of diarylmethane derivatives.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
J Org Chem
Año:
2017
Tipo del documento:
Article
País de afiliación:
China