Silylamido supported dinitrogen heterobimetallic complexes: syntheses and their catalytic ability.
Natl Sci Rev
; 8(12): nwaa290, 2021 Dec.
Article
en En
| MEDLINE
| ID: mdl-34987834
ABSTRACT
Molybdenum dinitrogen complexes supported by monodentate arylsilylamido ligand, [Ar(Me3Si)N]3MoN2Mg(THF)2[N(SiMe3)Ar] (5) and [Ar(Me3Si)N]3MoN2SiMe3 (6) (Ar = 3,5-Me2C6H3) were synthesized and structurally characterized, and proved to be effective catalysts for the disproportionation of cyclohexadienes and isomerization of terminal alkenes. The 1H NMR spectrum suggested that the bridging nitrogen ligand remains intact during the catalytic reaction, indicating possible catalytic ability of the Mo-N=N motif.
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1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Natl Sci Rev
Año:
2021
Tipo del documento:
Article
País de afiliación:
China