Effects of asphaltenes on the photolytic and toxic behavior of bitumen and conventional oil products on saltwater.

ABSTRACT

The effects of asphaltenes on the photolytic and toxic behavior of petroleum oil on seawater was investigated by exposing five original oils and their maltenes to solar irradiation for seven days. Polycyclic aromatic hydrocarbons (PAHs) experienced the fastest photo-oxidation, but negligible photolytic loss was observed for most normal alkanes and all the petroleum biomarkers from tri-cyclic to pentyl-cyclic terpanes in the test total oil and maltenes. The removal of most PAHs from some maltenes was greater than the corresponding total oils. Deasphalting process did not affect the characteristics of naphthenic acid fraction components (NAFCs) in all control samples. In all test oils, solar irradiation formed abundant NAFCs, in particular those only containing oxygen as the heteroatoms (Oo species). The formed Oo species were abundant in congeners having highly saturated congeners, and shifted to a lighter carbon number after exposed. Deasphalting process significantly enhanced the formation of Oo species (o from 2 to 4) for all test oils, in particular for the Cold Lake Blend and Bunker C. The toxicity of exposed maltenes was generally higher than the exposed total oil for most oils, suggesting the aqueous toxicity level was positively related to the formed NAFC intermediates.