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Aqueous transfer of colloidal metal oxide nanocrystals via base-driven ligand exchange.
Lakhanpal, Vikram S; Zydlewski, Benjamin Z; Gan, Xing Yee; Celio, Hugo; Jhong, Huei-Ru Molly; Ofosu, Charles K; Milliron, Delia J.
Afiliación
  • Lakhanpal VS; McKetta Department of Chemical Engineering, University of Texas at Austin, Austin, Texas 78712, USA.
  • Zydlewski BZ; Department of Chemistry, University of Texas at Austin, Austin, Texas 78712, USA. milliron@che.utexas.edu.
  • Gan XY; McKetta Department of Chemical Engineering, University of Texas at Austin, Austin, Texas 78712, USA.
  • Celio H; Texas Materials Institute and Materials Science and Engineering Program, The University of Texas at Austin, Austin, TX 78712, USA.
  • Jhong HM; McKetta Department of Chemical Engineering, University of Texas at Austin, Austin, Texas 78712, USA.
  • Ofosu CK; Department of Chemistry, University of Texas at Austin, Austin, Texas 78712, USA. milliron@che.utexas.edu.
  • Milliron DJ; McKetta Department of Chemical Engineering, University of Texas at Austin, Austin, Texas 78712, USA.
Chem Commun (Camb) ; 58(68): 9496-9499, 2022 Aug 23.
Article en En | MEDLINE | ID: mdl-35920348
A general method is developed for removal of native nonpolar oleate ligands from colloidal metal oxide nanocrystals of varying morphologies and compositions. Ligand stripping occurs by phase transfer into potassium hydroxide solution, yielding stable aqueous dispersions with little nanocrystal aggregation and without significant changes to the nanomaterials' physical or chemical properties. This method enables facile fabrication of conductive films of ligand-free nanocrystals.
Asunto(s)

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Óxidos / Nanopartículas del Metal Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: Estados Unidos

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Asunto principal: Óxidos / Nanopartículas del Metal Idioma: En Revista: Chem Commun (Camb) Asunto de la revista: QUIMICA Año: 2022 Tipo del documento: Article País de afiliación: Estados Unidos