Sacrificial-Hydroxamate-Enabled Sizable Crystallization of Scandium Carboxylate Metal-Organic Frameworks.

Wu, Wenjing; Tang, Wenlei; Shao, Zhen-Wu; Feng, Xuan; Xiong, Li; Xiong, Chaozhi; Lai, Qiuxue; Liu, Chong

Wu, Wenjing; Tang, Wenlei; Shao, Zhen-Wu; Feng, Xuan; Xiong, Li; Xiong, Chaozhi; Lai, Qiuxue; Liu, Chong.

Afiliación

Wu W; School of Chemical Engineering, Sichuan University, Chengdu 610065, China.
Tang W; National Key Laboratory for Nuclear Fuel and Materials, Nuclear Power Institute of China, Chengdu 610213, China.
Shao ZW; School of Chemical Engineering, Sichuan University, Chengdu 610065, China.
Feng X; School of Chemical Engineering, Sichuan University, Chengdu 610065, China.
Xiong L; School of Chemical Engineering, Sichuan University, Chengdu 610065, China.
Xiong C; School of Chemical Engineering, Sichuan University, Chengdu 610065, China.
Lai Q; School of Chemical Engineering, Sichuan University, Chengdu 610065, China.
Liu C; School of Chemical Engineering, Sichuan University, Chengdu 610065, China.

Inorg Chem ; 63(4): 1720-1724, 2024 Jan 29.

Article en En | MEDLINE | ID: mdl-38214245

ABSTRACT

ABSTRACT

Starting from labile hydroxamic acid ligands that are strong chelators, here, we implemented a sacrificial modulating strategy to prepare a series of scandium carboxylate metal-organic frameworks. Overcoming conventional syntheses that use excessive carboxylate modulators, the present strategy greatly reduces the organics required and produces large single crystals of several Sc-MOFs for X-ray crystallography.

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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Inorg Chem Año: 2024 Tipo del documento: Article País de afiliación: China

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