Red-Light-Driven Bifunctionalization of Styrene Derivatives.
J Org Chem
; 89(11): 8178-8184, 2024 Jun 07.
Article
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| MEDLINE
| ID: mdl-38803054
ABSTRACT
A red-light-activated phthalocyanine ruthenium complex has been designed as a catalyst for the bifunctionalization of styrene derivatives. The combination of a trifluoromethylation agent resistant to nucleophiles and various nucleophiles facilitates the concurrent incorporation of a trifluoromethyl group and various functional groups onto the double bond of the substrate. This reaction demonstrates the utility of mild, low-energy, and highly transmissive long-wavelength light for intricate molecular transformations in a one-pot procedure.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
J Org Chem
Año:
2024
Tipo del documento:
Article
País de afiliación:
Japón