Vertically-Aligned Card-House Structure for Composite Solid Polymer Electrolyte with Fast and Stable Ion Transport Channels.

All-solid-state lithium batteries (ASSLBs) are highly promising as next-generation energy storage devices owing to their potential for great safety and high energy density. This work demonstrates that composite solid polymer electrolyte with vertically-aligned card-house structure can simultaneously improve the high rate and long-term cycling performance of ASSLBs. The vertical alignment of laponite nanosheets creates fast and uniform Li+ ion transport channels at the nanosheets/polymer interphase, resulting in high ionic conductivity of 8.9 × 10-4 S cm-1 and Li+ transference number of 0.32 at 60 °C, as well as uniformly distributed solid electrolyte interphase. Such electrolyte is characterized by high mechanical strength, low flammability, excellent structural stability and stable ion transport channels. In addition, the ASSLB cell with the electrolyte and LiFePO4 cathode delivers a high discharge specific capacity of 124.8 mAh g-1 , which accounts for 85.6% of its initial capacity after 500 cycles at 1C. The reasonable design through structural control strategy by interconnecting the vertically-aligned nanosheets open a way to fabricate high performance composite solid polymer electrolytes.

Tailoring Pore Structures of 3D Printed Cellular High-Loading Cathodes for Advanced Rechargeable Zinc-Ion Batteries.

Developing high-loading cathodes with superior electrochemical performance is desirable but challenging in aqueous zinc-ion batteries (ZIBs) for commercialization. Advanced 3D printing of cellular and hierarchical porous cathodes with high mass loading for superior ZIBs is explored here. To obtain a high-performance 3D printable ink, a composite material of iron vanadate and reduced holey graphene oxide is synthesized as the ink component. A cellular cathode with hierarchical porous architecture for aqueous ZIBs is then designed and fabricated by 3D printing for the first time. The unique structures of 3D printed composite cathode provide interpenetrating transmission paths as well as channels for electrons and ions. 3D printed cathodes with high mass loading over 10 mg cm-2 exhibit a high specific capacity of 344.8 mAh g-1 at 0.1 A g-1 and deliver outstanding cycling stability over 650 cycles at 2 A g-1 . In addition, the printing strategy enables the ease increase in mass loading up to 24.4 mg cm-2 , where a remarkably high areal capacity of 7.04 mAh cm-2 is reached. The superior electrochemical performance paves the new way to design the state-of-the-art cathodes for ZIBs.

Direct Ink Writing of Li1.3 Al0.3 Ti1.7 (PO4 )3 -Based Solid-State Electrolytes with Customized Shapes and Remarkable Electrochemical Behaviors.

All-solid-state lithium batteries have received extensive attention due to their high safety and promising energy density and are considered as the next-generation electrochemical energy storage system. However, exploring solid-state electrolytes in customized geometries without sacrificing the ionic transport is significant yet challenging. Herein, various 3D printable Li1.3 Al0.3 Ti1.7 (PO4 )3 (LATP)-based inks are developed to construct ceramic and hybrid solid-state electrolytes with arbitrary shapes as well as high conductivities. The obtained inks show suitable rheological behaviors and can be successfully extruded into solid-state electrolytes using the direct ink writing (DIW) method. As-printed free-standing LATP ceramic solid-state electrolytes deliver high ionic conductivity up to 4.24 × 10-4  S cm-1 and different shapes such as "L", "T," and "+" can be easily realized without sacrificing high ionic transport properties. Moreover, using this printing method, LATP-based hybrid solid-state electrolytes can be directly printed on LiFePO4 cathodes for solid-state lithium batteries, where a high discharge capacity of 150 mAh g-1 at 0.5 C is obtained. The DIW strategy for solid-state electrolytes demonstrates a new way toward advanced solid-state energy storage with the high ionic transport and customized manufacturing ability.

Three-dimensional mesoporous γ-Fe2O3@carbon nanofiber network as high performance anode material for lithium- and sodium-ion batteries.

Electrode materials that can function well in both lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) are desirable for electrochemical energy storage applications, especially under high rate. In this work, a three-dimensional (3D) mesoporous γ-Fe2O3@carbon nanofiber (γ-Fe2O3@CNF) mat has been successfully synthesized by sol-gel based electrospinning and carbonization. It delivers a specific capacity of 820 mAh g-1 at 0.5 C after 250 cycles, 430 mAh g-1 at 6 C after 1000 cycles, and 222 mAh g-1 at ultrahigh rate of 60 C for LIBs, while for SIBs it delivers a specific capacity of 360 mAh g-1 at 1 C after 1000 cycles and 130 mAh g-1 at 60 C. Besides, the result of ex situ microstructure examination shows the polycrystalline nature of γ-Fe2O3 nanoparticle still exists in LIB even after 1000 cycles, while it vanishes in SIB, suggesting that the relatively larger volume expansion occurred during Na+ insertion/deinsertion, resulting in pulverization of the particles. The CNFs maintained their pristine 3D network structure after the charge/discharge, which demonstrated the critical role of a robust conductive electrode in promoting fast Li+/Na+ transportation. More importantly, they act as an electrical bridge between Li+/Na+ and γ-Fe2O3 nanoparticles, therefore suppressing the cell impedance growth and γ-Fe2O3 volume expansion, resulting in the enhancement in both cyclic and rate capability.

One-pot synthesis of in-situ carbon-coated Fe3O4 as a long-life lithium-ion battery anode.

Fe3O4 has been regarded as a promising anode material for lithium-ion batteries (LIBs) due to its high theoretical capacity, low cost, and environmental friendliness. In this work, we present a one-pot reducing-composite-hydroxide-mediated (R-CHM) method to synthesize in situ carbon-coated Fe3O4 (Fe3O4@C) at 280 °C using Fe(NO3)3 · 9H2O and PEG800 as raw materials and NaOH/KOH as the medium. The as-prepared Fe3O4 octahedron has an average size of 100 nm in diameter, covered by a carbon layer with a thickness of 3 nm, as revealed by FESEM and HRTEM images. When used as anode materials in LIBs, Fe3O4@C exhibited an outstanding rate capability (1006, 918, 825, 737, 622, 455 and 317 mAh g-1 at 0.1, 0.2, 0.5, 0.8, 1.0, 1.5 and 2.0 A g-1). Moreover, it presented an excellent cycling stability, with a retained capacity of 261 mAh g-1 after 800 cycles under an extremely high specific current density of 2.0 A g-1. Such results indicate that Fe3O4@C can provide a new route into the development of long-life electrodes for future rechargeable LIBs. Importantly, the R-CHM developed in our work can be extended for the synthesis of other carbon-coated electrodes for LIBs and functional nanostructures for broader applications.

Controllable synthesis of Cu2O/Cu composites with stable photocatalytic properties.

Here we reported a facile approach to synthesize Cu2O/Cu composite particles by one-step sono-chemical process. The content of Cu in the Cu2O/Cu composites can be easily controlled by adjusting the synthesis time. Phase, morphology and optical properties of the products were carried out by X-ray diffraction (XRD), field-emission scanning electron microscopy (FSEM), transmission electron microscope (TEM), ultraviolet-visible (UV-vis) spectroscopy and nitrogen adsorption apparatus. Using photocatalytic degradation of Methyl orange (MeO) dye under visible-light illumination, we have investigated the influence of Cu on the photocatalytic activity of Cu2O, to find out its potential application in waste water treatment. Especially, the stability of the photocatalyst was confirmed using reclaimed Cu2O/Cu in ten successive runs. Results demonstrated clearly that Cu2O/Cu were stable and resistant to photocorrosion during the photocatalytic oxidation of organic compounds, indicating that these Cu2O/Cu composites are promising candidates for pollutant processing.

Designing the Interface Layer of Solid Electrolytes for All-Solid-State Lithium Batteries.

Li1.3Al0.3Ti1.7(PO4)3 (LATP) is one of the most attractive solid-state electrolytes (SSEs) for application in all-solid-state lithium batteries (ASSLBs) due to its advantages of high ionic conductivity, air stability and low cost. However, the poor interfacial contact and slow Li-ion migration have greatly limited its practical application. Herein, a composite ion-conducting layer is designed at the Li/LATP interface, which a MoS2 film is constructed on LATP via chemical vapor deposition, followed by the introduction of a solid polymer (SP) liquid precursor to form a MoS2@SP protective layer. This protective layer not only achieves a lower Li-ion migration energy barrier, but also adsorbs more Li-ion, which is able to promote interfacial ion transport and improve interfacial contacts. Thanks to the improved migration and adsorption of Li-ion, the Li symmetric cell containing LATP-MoS2@SP exhibits a stable cycle of more than 1200 h at 0.1 mA cm-2. More remarkably, the capacity retention of the full cell assembled with LiFePO4 cathode is as high as 86.2% after 400 cycles at 1 C. This work provides a design strategy for significantly improving unstable interfaces of SSEs and realizing high-performance ASSLBs.

Sexual experiences of postmenopausal women in China: a qualitative study.

Background: Sexual dysfunction is common among postmenopausal women and can have a significant negative impact on quality of life. Aim: This study aimed to explore perceptions, experiences, and coping strategies related to sex among postmenopausal women in China. Methods: We used phenomenologic qualitative methods in this study. On the basis of purposive sampling and the data saturation principle, 21 volunteers from a community cohort study were selected for semistructured interviews. The data were analyzed and themes were extracted. Outcomes: Thematic codes pertaining to sexual experiences and coping strategies were defined and assessed in this study. Results: Four themes and 12 subthemes were extracted from the interview data. The sexual concepts were relatively conservative for most of the Chinese women; the majority experienced physical and psychological distress with respect to sex, although negative and positive psychological experiences were described. The women often passively accepted and adapted to negative changes to their sex lives during the postmenopause period. Clinical Implications: This study highlights the importance of and need for effective dissemination of sexual health-related knowledge and the opening of appropriate communication channels. Strengths and Limitations: By using a qualitative approach, this study provides individuals with the opportunity to describe their cognition and attitudes toward sexuality. Limitations include limited generalizability, as is true for most qualitative research. Additionally, the study is based solely on the female perspective and cannot fully reflect the sex life of couples. Conclusion: The sexual experiences of our respondents exhibited distinct Chinese cultural characteristics. The interviews show the importance of paying attention to postmenopausal women's sexual health and providing relevant professional support and guidance to improve women's overall health-related quality of life.

Multi-Channel Engineering of 3D Printed Zincophilic Anodes for Ultrahigh-Capacity and Dendrite-Free Quasi-Solid-State Zinc-Ion Microbatteries.

Zinc-ion microbatteries (ZIMBs) are regarded as one of most promising miniaturized energy storage candidates owing to their high safety, compatible device size, superior energy density, and cost efficiency. Nevertheless, the zinc dendrite growth during charging/discharging and the inflexible device manufacturing approach seriously restrict practical applications of ZIMBs. Herein, we report a unique material extrusion 3D printing approach with reinforced zincophilic anodes for ultrahigh-capacity and dendrite-free quasi-solid-state ZIMBs. A 3D printed N-doped hollow carbon nanotube (3DP-NHC) multichannel host is rationally designed for desirable dendrite-free zinc anodes. Favorable structural metrics of 3DP-NHC hosts with abundant porous channels and high zincophilic active sites enhance the ion diffusion rate and facilitate uniform zinc deposition behavior. Rapid zinc-ion migration is predicted through molecular dynamics, and zinc dendrite growth is significantly suppressed with homogeneous zinc-ion deposition, as observed by in situ optical microscopy. 3D printed symmetric zinc cells exhibit an ultralow polarization potential, a glorious rate performance, and a stable charging/discharging process. Accordingly, 3D printed quasi-solid-state ZIMBs achieve an outstanding device capacity of 11.9 mA h cm-2 at 0.3 mA cm-2 and superior cycling stability. These results reveal a feasible approach to effectively restrain zinc dendrite growth and achieve high performance for state-of-the-art miniaturized energy storage devices.

Microwave-assisted in situ ring-opening polymerization of ε-caprolactone in the presence of modified halloysite nanotubes loaded with stannous chloride.

Polycaprolactone (PCL) has been widely applied for its excellent physicochemical properties, but it also has common problems with biopolymers. It is important to investigate energy-efficient polymerization crafts and composite catalytic systems in the ring-opening polymerization (ROP) of ε-caprolactone (ε-CL) to prepare high-performance PCL matrix composites. In this study, a composite catalytic system of modified halloysite nanotubes loaded with stannous chloride (APTES-P-h-HNTs-SnCl2) was successfully synthesized via hydroxylation, calcination, silane coupling agent modification and physical loading. It was used to catalyze the microwave-assisted in situ ROP of ε-CL to synthesize PCL matrix nanocomposites with modified halloysite nanotubes (PCL-HNTs). The structure, morphology, polymerization, thermal properties and electrochemical performance of products were subsequently investigated. The results show that PCL-HNTs have been successfully synthesized with connected petal-like and porous structures. Compared with PCL, the film-forming and thermal properties of PCL-HNTs have been significantly improved. Moreover, PCL-HNTs have a potential application value in the field of solid polymer electrolytes (SPEs).

[The study of ultra-fine diamond powder used in magnetic head polishing slurry].

In the present paper, atomic absorption spectrometry(AAS), inductively-coupled plasma mass spectrometry (ICP-MS), transmission electron microscopy (TEM), X-ray diffraction (XRD) and laser Raman spectroscopy (RM) were employed to study the commercial ultra-fine diamond powders prepared by the static pressure-catalyst method and used in magnetic head polishing slurry. The results of AAS and ICP-MS indicated that there were silicon oxide, Fe, Ni, Al and some other metal elements in the ultra-fine powders. XRD patterns showed the peaks of SiO2 at 2theta = 35.6 degrees, 39.4 degrees and 59.7 degrees and diamond sharp peaks in agreement with the results above. Diamond sharp peaks implied perfect crystal and high-hardness beneficial to high-efficiency in polishing. The broader Raman band of graphite at 1 592 cm(-1) observed by Raman analysis proved graphite existing in the diamond powders. In the TEM images, the size of ultra-fine powders was estimated between 0.1 and 0.5 microm distributed in a wide scope, however, sharp edges of the powder particles was useful to polish. The ultra-fine diamond powders have many advantages, for example, high-hardness, well abrasion performance, high-polishing efficiency and being useful in magnetic head polishing slurry. But, the impurities influence the polishing efficiency, shortening its service life and the wide distribution reduces the polishing precision. Consequently, before use the powders must be purified and classified. The purity demands is 99.9% and trace silicon oxide under 0.01% should be reached. The classification demands that the particle distribution should be in a narrower scope, with the mean size of 100 nm and the percentage of particles lager than 200 nm not over 2%.

Sepiolite/CNT/S@PANI composite with stable network structure for high performance lithium sulfur batteries.

Composite materials with a stable network structure consisting of natural sepiolite (Sep) powders, carbon nanotubes (CNTs) and conductive polymer (PANI) have been successfully synthesized using a simple vacuum heat treatment and chemical oxidation method, and they have been used as cathode materials for lithium sulfur batteries. It is found that Sep/CNT/S@PANI composites possess high initial discharge capacity, good cyclic stability and good rate performance. The initial discharge capacity of the Sep/CNT/S@PANI-II composite is about 1100 mA h g-1 at 2C, and remained at 650 mA h g-1 after 300 cycles, and the corresponding coulombic efficiency is above 93%. Such performance is attributed to specific porous structure, outstanding adsorption characteristics, and excellent ion exchange capability of sepiolite, as well as excellent conductivity of CNT. Furthermore, the PANI coating has a pinning effect for sulfur, which enhances the utilization of the active mass and improves the cycling stability and the coulombic efficiency of the composites at high current rates.

[Effect of acupuncture on the activity of gastrointestinal electricity].

Based on the summarization of literatures on regulation of gastrointestinal electricity with acupuncture, the regulation effect of acupuncture, its influencing factors and its mechanism were analyzed in this article. It is found that the regulation effect can be influenced by many factors such as different acupuncture techniques, frequency, point selection, manipulations and the physical condition of the object. The effect of acupuncture appears great variety, which manifests as reinforced, inhibited or a kind of two-way regulation. And it is also held that the effect of acupuncture relies on the integrity of the nerve system. Nuclei, neurotransmitters, body fluid and gastrointestinal hormone also take part in the acupuncture effect. Therefore, studies on mechanism of acupuncture effect on gastrointestinal electricity should be strengthened in the future.