Band-tunable achromatic metalens based on phase change material.

Achromatic metalens have the potential to significantly reduce the size and complexity of broadband imaging systems. A large variety of achromatic metalens has been proposed and most of them have the fixed achromatic band that cannot be actively modified. However, band-tunable is an important function in practical applications such as fluorescence microscopic imaging and optical detection. Here, we propose a bilayer metalens that can switch achromatic bands by taking the advantage of the high refractive index contrast of Sb2S3 between amorphous and crystalline state. By switching the state of Sb2S3, the achromatic band can be reversibly switched between the red region of visible spectrum (650-830 nm) and the near-infrared spectrum (830-1100 nm). This band-tunable design indicates a novel (to our knowledge) method to solve the problem of achromatic focusing in an ultrabroad band. The metalens have an average focusing efficiency of over 35% and 55% in two bands while maintaining diffraction-limited performance. Moreover, through proper design, we can combine different functionalities in two bands such as combining achromatic focusing and diffractive focusing. The proposed metalens have numerous potential applications in tunable displaying, detecting devices and multifunctional devices.

Dual-channel metasurfaces for independent and simultaneous display in near-field and far-field.

The operation of near-field and far-field can be employed to display holographic and nanoprinting images, which significantly improves the information density. Previous studies have proposed some approaches to display the images independently or simultaneously, but cannot satisfy these two characteristics in a single structure under the same incident light. Here, a single layer multifunctional metasurface is proposed to display a nanoprinting image and a holographic image independently and simultaneously. By tailoring the dimensions of each nanobricks and adopting different orientation angle, the amplitude and phase can be artificially designed. Moreover, enabled by the simulated annealing algorithm, we take the impact of both amplitude and phase of each nanobrick into consideration, which eliminates the unnecessary influence of amplitude on holographic image. Compared with previous work, our metasurfaces markedly improve the quality of holographic image with simple structures while not affecting the nanoprinting image. To be exact, it breaks the coupling between the near-field and far-field, achieving independent and simultaneous control of both fields. Our proposed metasurfaces carry characteristics of simple manufacture, little crosstalk, and great compactness, which provides novel applications for image displays, optical storage and information technology.

Novel 2D photocatalyst of copper-doped carbon quantum dot CD(Cu) loaded with ultrathin Ni-MOL for degradation of tetracycline.

Broadening the light absorption range and suppressing the carrier complexation are the two keys to enhance the photocatalytic activity. In this work, a novel two-dimensional (2D) photocatalyst was successfully prepared by modified hydrothermal method and applied in tetracycline (TC) degradation. The degradation rate of CD(Cu)-Ni-MOL for TC reached 93.5% within 60 min under the visible light condition. The improved photocatalytic performance of CD(Cu)-Ni-MOL was attributed to the constructed 2D layered structure and the special properties of CD(Cu). The doped Cu in carbon dots (CDs) exhibited excellent photocatalytic performance among the elements of Cu, Zn, Ni, Co and Fe. The order of photocatalytic performance improvement was Cu > Zn > Ni > Co > Fe. In addition, a possible degradation pathway for TC was proposed. This work confirms the great potential of CD(Cu)-Ni-MOL as a highly efficient photocatalyst in removing tetracycline pollutants in water.

Selective adsorption behavior of Cd2+ imprinted acrylamide-crosslinked-poly(alginic acid) magnetic polymers: fabrication, characterization, adsorption performance and mechanism.

Poly(acrylamide) grafted and glutaraldehyde-crosslinked alginic acid nano-magnetic adsorbent (AAMA) was prepared by selecting Cd2+ as a template ion. Scanning electron microscope (SEM), thermo-gravimetric analyzer (TGA), vibrating sample magnetometer (VSM) and infrared spectroscopy (IR) were used to characterize the morphology and structure of AAMA. The adsorption of AAMA for different metal ions was compared and the impact of various factors for adsorption of Cd2+ was systematically investigated. These results suggested that the AAMA was the aggregates of Fe3O4 nanoparticles with a diameter of about 50-100 nm and had selectivity for Cd2+ adsorption. The maximum adsorption capacity for Cd2+ is 175 mg/g at pH 5.0 and 303 K. The experimental data were well described by the Langmuir isotherm model and pseudo-second-order model. The parameters of adsorption thermodynamics concluded that the adsorption progress is spontaneous and endothermic in nature. The parameters of adsorption activation energy suggested that there is physical adsorption and chemisorption on the adsorption of metal ions. AAMA could be regenerated by EDTA and still keep 71% adsorption capacity in the fifth consecutive adsorption-regeneration cycle. Therefore, AAMA would be useful as a selective and high adsorption capacity nano-magnetic adsorbent in the removal of Cd2+ from wastewater.

Ultrastiff metamaterials generated through a multilayer strategy and topology optimization.

Metamaterials composed of different geometrical primitives have different properties. Corresponding to the fundamental geometrical forms of line, plane, and surface, beam-, plate-, and shell-based lattice metamaterials enjoy many advantages in many aspects, respectively. To fully exploit the advantages of each structural archetype, we propose a multilayer strategy and topology optimization technique to design lattice metamaterial in this study. Under the frame of the multilayer strategy, the design space is enlarged and diversified, and the design freedom is increased. Topology optimization is applied to explore better designs in the larger and diverse design space. Beam-plate-shell-combined metamaterials automatically emerge from the optimization to achieve ultrahigh stiffness. Benefiting from high stiffness, energy absorption performances of optimized results also demonstrate substantial improvements under large geometrical deformation. The multilayer strategy and topology optimization can also bring a series of tunable dimensions for lattice design, which helps achieve desired mechanical properties, such as isotropic elasticity and functionally grading material property, and superior performances in acoustic tuning, electrostatic shielding, and fluid field tuning. We envision that a broad array of synthetic and composite metamaterials with unprecedented performance can be designed with the multilayer strategy and topology optimization.

Three-Channel Near-Field Display and Encryption Based on a Polarization Multiplexed Metasurface.

Multichannel metasurfaces are becoming a significant trend in the field of optical encryption due to their excellent manipulation of optical wavefronts. However, existent multichannel metasurfaces for optical encryption mostly implement only two channels in the near-field, or three channels by combining the near- and far-field. In this paper, we propose and simulate a three-channel metasurface that works entirely in the near-field and uses the polarization state of the incident light, left circularly polarized (LCP) light, right circularly polarized (RCP) light, and linearly polarized (LP) light as the security key. The metasurface consists of two types of nanostructures that work as a polarizer and a quarter-wave plate, providing an additional degree of freedom for encoding that enables independent near-field display at 633 nm wavelength incident light. The proposed three-channel metasurface has the advantages of high information density and high security, which will pave the way for multi-channel applications such as ultracompact displays, optical encryption, and information storage.

Ni-MOL/In2Se3 heterostructure construction with mixed metal (Ti/Ni) for efficient photocatalytic tetracycline degradation.

To investigate the mechanism of bimetallic 2-dimension (2D) catalyst existing in the current photocatalytic degradation process, the tetracycline (TC) degradation performance and mechanism by bimetallic 2D photocatalyst was studied extensively. Nickel metal-organic layer (Ni-MOL) and In2Se3, a typical 2D semiconductor photocatalyst, shows great potential for photocatalytic degradation of TC. Herein, an In2Se3 assisted Ni-MOL composite bimetallic photocatalyst was assembled, of which could obtain the degradation rate of 96.4% within 90 min for TC under visible light. Ni-MOL was the main active site for TC degradation by photo-induced holes which located at the Ni atom active site during the photocatalytic process. The role of In2Se3 and the element of Ti in Ni-MOL was to assist Ni-MOL by providing more photo-induced carriers and inhibiting carrier recombination. This work makes a contribution to the application of 2D bimetallic photocatalytic in TC degradation.

Three-Channel Metasurfaces for Multi-Wavelength Holography and Nanoprinting.

Metasurfaces, employed to simultaneously generate nanoprinting and holographic images, have been extensively explored recently. Among them, multi-wavelength multiplexing in a single metasurface is often accompanied by dispersion and crosstalk, which hinder the display of multicolor patterns. Here, we propose an efficient phase method to decouple the wavelength and realize a three-channel display operating at different wavelengths. Holographic images appear in the far field with the illumination of two different circularly polarized lights while a nanoprinting image is reconstructed by inserting an orthogonal optical path with the illumination of linear polarization light. The proposed metasurface is only composed of four types of unit cells, which significantly decreases the complexity of fabrication and improves the information capacity. Benefiting from its different decoding strategies and capability of multi-wavelength control, this approach may develop broad applications in information encryption, security, and color display.