Highly Sensitive Diethylamine Detection at Room Temperature Using g-C3N4 Nanosheets Decorated with CuO Hollow Polyhedral Structures.

Chemiresistive-based metal oxide semiconductor (MOS) gas sensors are widely used in gas sensing due to their advantageous properties. Graphitic carbon nitride (g-C3N4) and metal oxide heterostructure materials can improve charge transport properties, selectivity, and sensitivity in MOS gas sensor materials. Herein, for the first time, CuO hollow polyhedral structures (HPSs) were synthesized via a hydrothermal technique and annealed at different temperatures, with the 400 °C annealed (CuO-400 HPSs) demonstrating remarkable sensing capabilities for diethylamine (DEA) gas at room temperature (RT). The x-g-C3N4 nanosheets were decorated with CuO HPSs in varying amounts (x = 0.8, 1.8, 2.1, and 3.1 wt %) and then annealed at 400 °C for x-g-C3N4-CuO-400 hollow polyhedral heterostructures (HPHSs). Indeed, among the synthesized samples, the 1.8%-g-C3N4-CuO-400 HPHSs have a higher sensitivity to DEA (resistance change in gas (Rg) and air (Ra); Rg/Ra= 65 @ 20 ppm), a low detection limit (Rg/Ra= 6 @ 500 ppb), wide dynamic response (Rg/Ra= 190 @ 80 ppm), strong stability (30 days), and 21.6 times higher sensitivity than pure CuO at RT toward 20 ppm of DEA. The exceptional gas-sensing behavior can be attributed to various factors, including controlled annealing conditions that result in the formation of well-defined structures and greater porosity, efficient charge transfer properties resulting from an optimized ratio of g-C3N4 to CuO in HPHSs, an abundance of defects, unsaturated Cu sites, and synergistic effects. The study presents a universal strategy for generating sensitive and selective g-C3N4-based composite materials for low-temperature gas sensors.

VS4 Nanodendrites with Narrow Bandgaps in Activating Dissolved Oxygen for Boosted Chemiluminescence and Hemin Detection by Unexpected Quenching.

Chemiluminescence (CL)-based analytical methods utilize luminophores that need to be activated with an oxidizing agent to trigger CL emission. Despite its susceptibility to decomposition when exposed to external light or trace metals, hydrogen peroxide (H2O2) has been widely used to develop chemiluminescent methods due to the limited number of suitable alternatives for activating chemiluminescent luminophores. Also, analytical methods based on the well-known luminol/H2O2 CL system have low sensitivity. Dissolved oxygen (DO) is a naturally abundant and environmentally benign alternative oxidant for luminol and other CL luminophores. However, DO alone is inactive and needs an efficient catalyst or a coreaction accelerator for its activation. Because of the narrow bandgap of VS4 (ca. 1.12 eV), it can facilitate fast electron-transfer kinetics with an acceptor molecule such as DO. Here, we introduce vanadium tetrasulfide (VS4) to boost CL for the first time. Under the optimized conditions, VS4 nanodendrite catalyzes the generation of reactive oxygen species by activating DO which subsequently reacts with luminol to generate intense CL. It enhances the CL intensity of luminol/DO by about 10,000 times. Surprisingly, hemin remarkably quenches the generated CL of luminol/DO/VS4 nanodendrites, which is completely opposite to its typical enhancement of luminol CL. Based on the remarkable concentration-dependent quenching of the luminol/DO/VS4 nanodendrite CL by hemin, we have developed a sensitive CL method that can selectively detect hemin in the linear concentration range of 1-250 nM and achieved a limit of detection of 0.11 nM. The practical utility of the developed method was demonstrated by the determination of hemin in a pharmaceutical drug for the treatment of acute intermittent porphyria and in human serum. This study demonstrates that VS4 holds great promise in analytical method development.

Fresnel incoherent compressive holography toward 3D videography via dual-channel simultaneous phase-shifting interferometry.

Fresnel incoherent correlation holography (FINCH) enables high-resolution 3D imaging of objects from several 2D holograms under incoherent light and has many attractive applications in motionless 3D fluorescence imaging. However, FINCH has difficulty implementing 3D imaging of dynamic scenes since multiple phase-shifting holograms need to be recorded for removing the bias term and twin image in the reconstructed scene, which requires the object to remain static during this progress. Here, we propose a dual-channel Fresnel noncoherent compressive holography method. First, a pair of holograms with π phase shifts obtained in a single shot are used for removing the bias term noise. Then, a physic-driven compressive sensing (CS) algorithm is used to achieve twin-image-free reconstruction. In addition, we analyze the reconstruction effect and suitability of the CS algorithm and two-step phase-shift filtering algorithm for objects with different complexities. The experimental results show that the proposed method can record hologram videos of 3D dynamic objects and scenes without sacrificing the imaging field of view or resolution. Moreover, the system refocuses images at arbitrary depth positions via computation, hence providing a new method for fast high-throughput incoherent 3D imaging.

Much Stronger Chemiluminescence of 9-Mesityl-10-methylacridinium Ion than Lucigenin at Neutral Conditions for Co2+ Detection.

9-Mesityl-10-methylacridinium ion (Acr+-Mes) is a donor-acceptor molecule with a much longer lifetime and a higher energy electron transfer excited state than natural photosynthetic reaction centers. Unlike lucigenin with a coplanar geometry, Acr+-Mes has an orthogonal geometry. There is no π conjugation between Acr+ and Mes. Due to its special electron donor-acceptor structure, it does not rely on strong alkalinity to generate an electron transfer state like lucigenin, which makes it possible to achieve chemiluminescence (CL) under weakly alkaline or neutral conditions. In this study, we report Acr+-Mes CL for the first time. Acr+-Mes generates about 400 times stronger CL intensity than lucigenin under neutral conditions (pH = 7) using KHSO5 as the coreactant. Moreover, Co2+ can enhance Acr+-Mes/KHSO5 CL remarkably. Acr+-Mes/KHSO5 CL enables Co2+ detection with a linear range of 0.5-500 nM and a limit of detection of 28 pM (S/N = 3). This method was tested for the detection of Co2+ in lake water, and the standard recovery rate of 96.8-107% was achieved. This study provides a new way to develop efficient CL systems in neutral solutions.

Remarkably Enhanced Luminol/H2O2 Chemiluminescence with Excellent Peroxidase-like Activity of FeCoNi-based Metal-Organic Xerogels for the Sensitive Detection of Dopamine.

Metal-organic gels (MOGs) are a category of metal-organic smart soft materials with large specific surface areas, loose porous structures, and open metal active sites. In this work, trimetallic Fe(III)Co(II)Ni(II)-based MOGs (FeCoNi-MOGs) were synthesized at room temperature via a simple and mild one-step procedure. Fe3+, Co2+, and Ni2+ were the three central metal ions in it, while 1,3,5-benzenetricarboxylic acid (H3BTC) served as the ligand. The solvent enclosed in it was then removed by freeze-drying to get the corresponding metal-organic xerogels (MOXs). The as-prepared FeCoNi-MOXs have excellent peroxidase-like activity and can significantly enhance luminol/H2O2 chemiluminescence (CL) by more than 3000 times, which is very effective compared with other reported MOXs. Based on the inhibitory effect of dopamine on the CL of the FeCoNi-MOXs/luminol/H2O2 system, a simple, rapid, sensitive, and selective CL method for dopamine detection was established with a linear range of 5-1000 nM and a limit of detection of 2.9 nM (LOD, S/N = 3). Furthermore, it has been effectively used for the quantitative measurement of dopamine in dopamine injections and human serum samples, with a recovery rate of 99.5-109.1%. This research brings up prospects for the application of MOXs with peroxidase-like activity in CL.

Generation and measurement of irregular polygonal perfect vortex optical beam based on all-dielectric geometric metasurface.

The perfect optical vortex (POV) beam carrying orbital angular momentum with topological charge-independent radial intensity distribution possesses ubiquitous applications in optical communication, particle manipulation, and quantum optics. But the mode distribution of conventional POV beam is relatively single, limiting the modulation of the particles. Here, we originally introduce the high-order cross-phase (HOCP) and ellipticity γ into the POV beam and construct all-dielectric geometric metasurfaces to generate irregular polygonal perfect optical vortex (IPPOV) beams following the trend of miniaturization and integration of optical systems. By controlling the order of the HOCP, conversion rate u, and ellipticity factor γ, various shapes of IPPOV beams with different electric field intensity distributions can be realized. In addition, we analyze the propagation characteristics of IPPOV beams in free-space, and the number and rotation direction of bright spots at the focal plane give the magnitude and sign of the topological charge carried by the beam. The method does not require cumbersome devices or complex calculation process, and provides a simple and effective method for simultaneous polygon shaping and topological charge measurement. This work further improves the beam manipulation ability while maintaining the characteristics of the POV beam, enriches the mode distribution of the POV beam, and provides more possibilities for particle manipulation.

Singular multi-wavelength and multi-waveband transparencies generated by P T-symmetric dumbbell optical waveguide networks.

In this paper, we investigate the singular multi-wavelength and multi-waveband transparencies generated by P T-symmetric dumbbell optical waveguide networks composed of two materials, and obtain the number regularity for the transparency wavelengths of one-unit-cell system and the general relationships for the transmission and reflection coefficients of multi-unit-cell systems. Consequently, three types of exact transparencies produced by multi-unit-cell systems are found based on the aforementioned formulas: (i)exact multi-wavelength unidirectional or bidirectional transparency as the same as those of one-unit-cell system; (ii)exact multi-wavelength bidirectional transparency at which one-unit-cell system cannot produce exact transparency, generated by adjusting the number of unit cells; (iii)exact multi-wavelength bidirectional transparency at which one-unit-cell system produces exact transparency, also generated by adjusting the number of unit cells. It provides theoretical foundations for developing highly sensitive and multi-wavelength optical filters. On the other hand, we also discover that multi-unit-cell systems can create approximate multi-waveband bidirectional transparencies by adjusting the number of unit cells, which provides scientific support for developing high-performance optical stealth devices.

Synthesis of a Novel Electrochemical Probe for the Sensitive and Selective Detection of Biothiols and Its Clinical Applications.

The ability to estimate and quantify biothiols in biological fluids is very significant for attaining a detailed understanding of biothiols-related pathological diseases. Most of the developed methods for biothiols detection are not suitable for this purpose owing to their low sensitivity, poor selectivity, and long experimental procedures. In this study, a novel and simple structure electrochemical probe has been synthesized for the first time for the selective determination of biothiols. The developed probe is based on using 2,4-dinitrobenzenesulfonyl moiety (DNBS) as a selective recognition moiety for biothiols. The electrochemical probe was successfully fabricated through a facile one-step reaction between 2,4-dinitrobenzenesulfonyl chloride (DNBS-Cl) and p-aminophenol. The successful synthesis of the probe was confirmed by using different characterization techniques such as an NMR spectroscopy, Fourier-transform infrared (FT-IR) spectroscopy, and mass spectrometry. Biothiols can selectively cleave the DNBS moiety through an aromatic nucleophilic substitution (ANS) reaction within 10 min to release p-aminophenol, which is a highly electrochemical active molecule that can be selectively detected easily by cyclic voltammetry at low potential. The probe has been employed for the quantification of cysteine, glutathione, and homocysteine with a LOD of 1.50, 3.48, and 4.67 µM, respectively. Excellent recoveries have been achieved in the range of 95.44-98.71% for the determination of the total biothiols in the human plasma sample.

Generation of multi-channel perfect vortex beams with the controllable ring radius and the topological charge based on an all-dielectric transmission metasurface.

The perfect vortex (PV) beam, characterized by carrying orbital angular momentum and a radial electric intensity distribution independent of the topological charge, has important applications in optical communication, particle manipulation, and quantum optics. Conventional methods of generating PV beams require a series of bulky optical elements that are tightly collimated with each other, adding to the complexity of optical systems. Here, making the amplitude of transmitted co-polarized and cross-polarized components to be constant, all-dielectric transmission metasurfaces with superimposed phase profiles integrating spiral phase plate, axicon and Fourier lens are constructed based on the phase-only modulation method. Using mathematical derivation and numerical simulation, multi-channel PV beams with controllable annular ring radius and topological charge are realized for the first time under circularly polarized light incidence combining the propagation phase and geometric phase. Meanwhile, perfect vector vortex beams are produced by superposition of PV beams under the incidence of left-handed circularly polarized and right-handed circularly polarized lights, respectively. This work provides a new perspective on generating tailored PV beams, increasing design flexibility and facilitating the construction of compact, integrated, and versatile nanophotonics platforms.

High-gain narrowband radio frequency signal amplifier based on a dual-loop optoelectronic oscillator.

A novel photonic-assisted method for radio frequency (RF) signal amplification with high-gain and narrowband based on a dual-loop optoelectronic oscillator (OEO) is proposed and experimentally demonstrated. In the proposed system, the low-power RF signal is injected into a dual-loop OEO which is below the threshold oscillation state. And the maximum gain is obtained when the frequency of the RF signal matches with the potential oscillation mode of the dual-loop OEO. The approach provides an average gain greater than 22 dB for the RF signal which matches with oscillation mode. After amplification, the signal-to-noise ratio (SNR) turns out to be 40 dB. Furthermore, the 3 dB bandwidth of the suggested system can be narrower than 1.2 kHz which can effectively remove the out-of-band noise and spurious effects. Meanwhile, the performance of sensitivity and phase noise are also investigated.

Rational number harmonic mode-locked dual-loop optoelectronic oscillator with low supermode noise and low intermodulation distortions.

A rational number harmonic mode-locked dual-loop optoelectronic oscillator (RHML-DL-OEO) is proposed and experimentally demonstrated. In the proposed system, an external radio frequency (RF) signal and a feedback oscillating microwave signal drive two arms of a dual-drive Mach-Zehnder modulator (DMZM). Mode locking is realized by frequency detuning. The larger effective free spectrum range (FSR) and higher side-mode suppression result from the Vernier effect effectively suppress supermode noise and intermodulation distortions (IMDs). Experimental results demonstrate that the microwave frequency comb (MFC) signals with repetition frequencies of 901.8 kHz, 2.3046 MHz and 5.3106 MHz are generated by 9th-, 23rd- and 53rd-order rational number harmonic mode-locking, respectively. Compared with the rational number harmonic mode-locked optoelectronic oscillator based on single-loop structure, the supermode noise suppression ratios of the scheme we propose are improved by 30.5 dB, 27.6 dB and 20.3 dB, respectively. Furthermore, the performance of single sideband (SSB) phase noise is also investigated.

Autofocusing self-imaging: symmetric Pearcey Talbot-like effect.

The Talbot-like effect of symmetric Pearcey beams (SPBs) is presented numerically and experimentally in the free space. Owing to the Talbot-like effect, the SPBs have the property of periodic, multiple autofocusing and self-healing. Meanwhile, the focusing positions and focusing times of SPBs are controlled by the beam shift factor and the distribution factors. Furthermore, the beam shift factor can also affect the Talbot-like effect and the Talbot period. It is believed that the results can diversify the application of the Talbot effect.

Multiple and off-axis optical bottles from the chirped circular Pearcey Gaussian vortex beams.

We introduce a new type of multiple and off-axis optical bottles (OBs) based on the chirped circular Pearcey Gaussian vortex beam. This kind of beam allows the generation of the OBs with a perfect bottle shape through coherent superposition. Also, we show that the number and the position of the OBs can be precisely and flexibly controlled. The experimental results agree well with our numerical simulations, and we observe stable trapping of the mesocarbon microbeads particles by the proposed bottle beam.

Band-tunable achromatic metalens based on phase change material.

Achromatic metalens have the potential to significantly reduce the size and complexity of broadband imaging systems. A large variety of achromatic metalens has been proposed and most of them have the fixed achromatic band that cannot be actively modified. However, band-tunable is an important function in practical applications such as fluorescence microscopic imaging and optical detection. Here, we propose a bilayer metalens that can switch achromatic bands by taking the advantage of the high refractive index contrast of Sb2S3 between amorphous and crystalline state. By switching the state of Sb2S3, the achromatic band can be reversibly switched between the red region of visible spectrum (650-830 nm) and the near-infrared spectrum (830-1100 nm). This band-tunable design indicates a novel (to our knowledge) method to solve the problem of achromatic focusing in an ultrabroad band. The metalens have an average focusing efficiency of over 35% and 55% in two bands while maintaining diffraction-limited performance. Moreover, through proper design, we can combine different functionalities in two bands such as combining achromatic focusing and diffractive focusing. The proposed metalens have numerous potential applications in tunable displaying, detecting devices and multifunctional devices.

Dual-channel metasurfaces for independent and simultaneous display in near-field and far-field.

The operation of near-field and far-field can be employed to display holographic and nanoprinting images, which significantly improves the information density. Previous studies have proposed some approaches to display the images independently or simultaneously, but cannot satisfy these two characteristics in a single structure under the same incident light. Here, a single layer multifunctional metasurface is proposed to display a nanoprinting image and a holographic image independently and simultaneously. By tailoring the dimensions of each nanobricks and adopting different orientation angle, the amplitude and phase can be artificially designed. Moreover, enabled by the simulated annealing algorithm, we take the impact of both amplitude and phase of each nanobrick into consideration, which eliminates the unnecessary influence of amplitude on holographic image. Compared with previous work, our metasurfaces markedly improve the quality of holographic image with simple structures while not affecting the nanoprinting image. To be exact, it breaks the coupling between the near-field and far-field, achieving independent and simultaneous control of both fields. Our proposed metasurfaces carry characteristics of simple manufacture, little crosstalk, and great compactness, which provides novel applications for image displays, optical storage and information technology.

Strong enhancement of Goos-Hänchen shift through the resonant optical tunneling effect.

The resonant optical tunneling effect (ROTE) originates from the frustrated total reflection effect because unique transmission characteristics are used to study high-sensitivity sensors. In this study, we theoretically demonstrated that choosing a suitable transmission gap made it possible for the ROTE structure based on hexagonal boron nitride and graphene to obtain a large Goos-Hänchen shift as high as tens of thousands of times the incident wavelength at a specific incident angle. The amplitude of the Goos-Hänchen shift was found to be sensitive to the central layer thickness but was also modulated by the tunneling gap on both sides. In addition, adjusting the chemical potential and relaxation time of the graphene sheets could alter the Goos-Hänchen shift. Our work provides a new way to explore the Goos-Hänchen effect and opens the possibility for the application of high-precision measurement technology based on the ROTE.

Shaping autofocusing Airy beams through the modification of Fourier spectrum.

A new type of Airy beam arisen from the modification of Fourier spectrum is introduced numerically and experimentally. The autofocusing Airy beam (AAB) exhibits the features of off-axis autofocusing and transverse self-accelerating, producing a needle-like focus in the longitudinal direction and a tiny focal spot at the focusing plane. Furthermore, the focusing properties such as focusing position, focal spot size, focusing intensity and depth of focus can be adjusted by modulating parameters of the AAB. Experimental demonstrations of particle trapping and manipulation with the AAB are also presented. The number of trapped particles can be controlled by changing the focal spot size at the autofocusing plane. Our results offer practical applications in particle manipulation, fluorescent imaging technology, laser spectroscopy and so on.

Communication wavelength investigation of bound states in the continuum of one-dimensional two-material periodic ring optical waveguide network.

In this study, a one-dimensional (1D) two-material period ring optical waveguide network (TMPROWN) was designed, and its optical properties were investigated. The key characteristics observed in the 1D TMPROWN include the following: (1) Bound states in continuum (BICs) can be generated in the optical waveguide network. (2) In contrast to the BICs previously reported in optical structures, the range of the BICs generated by the 1D TMPROWN is not only larger, but also continuous. This feature makes it possible for us to further study the electromagnetic wave characteristics in the range of the BICs. In addition, we analyzed the physical mechanisms of the BICs generated in the 1D TMPROWN. The 1D TMPROWN is simple in structure, demonstrates flexibility with respect to adjusting the frequency band of the BICs, and offers easy measurement of the amplitude and phase of electromagnetic waves. Hence, further research on high-power super luminescent diodes, optical switches, efficient photonic energy storage, and other optical devices based on the 1D TMPROWN designed in this study is likely to have implications in a broad range of applications.

Genome-wide identification of PIP5K in wheat and its relationship with anther male sterility induced by high temperature.

BACKGROUND: Phosphatidylinositol 4 phosphate 5-kinase (PIP5K) plays a key enzyme role in the inositol signal transduction system and has essential functions in plants in terms of growth, development, and stress responses. However, systematic studies on the wheat PIP5K gene family and its relation to male sterility have not been reported yet. RESULTS: Sixty-four TaPIP5K genes were identified. The TaPIP5K genes contained similar gene structures and conserved motifs on the same branches of the evolutionary tree, and their cis-regulatory elements were related to MeJA-responsiveness. Furthermore, 49 pairs of collinearity genes were identified and mainly subjected to purification selection during evolution. Synteny analyses showed that some PIP5K genes in wheat and the other four species shared a relatively conserved evolutionary process. The expression levels of many conservative TaPIP5K genes in HT-ms anthers were significantly lower than that in Normal anthers. In addition, HT-ms anthers have no dehiscence, and levels of OPDA and JA-ILE are significantly lower at the trinucleus stage. CONCLUSION: These results indicate that the PIP5K gene family may be associated with male sterility induced by HT, and the reduction of JA-ILE levels and the abnormal levels of these genes expression may be one reason for the HT-ms anthers having no dehiscence, ultimately leading to the abortion of the anthers.

Multifunctional metalens generation using bilayer all-dielectric metasurfaces.

Optical metasurfaces exhibit unprecedented ability in light field control due to their ability to locally change the phase, amplitude, and polarization of transmitted or reflected light. We propose a multifunctional metalens with dual working modes based on bilayer geometric phase elements consisting of low-loss phase change materials (Sb2Se3) and amorphous silicon (a-Si). In transmission mode, by changing the crystalline state of the Sb2Se3 scatterer, a bifocal metalens with an arbitrary intensity ratio at the telecommunication C-band is realized, and the total focusing efficiency of the bifocal metalens is as high as 78%. Also, at the resonance wavelength of the amorphous Sb2Se3 scatterer, the scatterer can be regarded as a half-wave plate in reflection mode. The multifunctional metalens can reversely converge incident light into a focal point with a focusing efficiency of up to 30%. The high focusing efficiency, dynamic reconfigurability, and dual working modes of the multifunctional metalens contribute to polarization state detection, optical imaging, and optical data storage. In addition, the bilayer geometric phase elements can be easily extended to multilayer, which significantly improves the capability of manipulating the incident light field.