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1.
Proc Natl Acad Sci U S A ; 116(28): 13768-13773, 2019 Jul 09.
Artículo en Inglés | MEDLINE | ID: mdl-31235596

RESUMEN

We present a mechanism for the anomalous behavior of the specific heat in low-temperature amorphous solids. The analytic solution of a mean-field model belonging to the same universality class as high-dimensional glasses, the spherical perceptron, suggests that there exists a cross-over temperature above which the specific heat scales linearly with temperature, while below it, a cubic scaling is displayed. This relies on two crucial features of the phase diagram: (i) the marginal stability of the free-energy landscape, which induces a gapless phase responsible for the emergence of a power-law scaling; and (ii) the vicinity of the classical jamming critical point, as the cross-over temperature gets lowered when approaching it. This scenario arises from a direct study of the thermodynamics of the system in the quantum regime, where we show that, contrary to crystals, the Debye approximation does not hold.

2.
Phys Rev Lett ; 126(12): 120603, 2021 Mar 26.
Artículo en Inglés | MEDLINE | ID: mdl-33834813

RESUMEN

We study a quantum interacting spin system subject to an external drive and coupled to a thermal bath of vibrational modes, uncorrelated for different spins, serving as a model for dynamic nuclear polarization protocols. We show that even when the many-body eigenstates of the system are ergodic, a sufficiently strong coupling to the bath may effectively localize the spins due to many-body quantum Zeno effect. Our results provide an explanation of the breakdown of the thermal mixing regime experimentally observed above 4-5 K in these protocols.

3.
Phys Rev Lett ; 116(1): 015902, 2016 Jan 08.
Artículo en Inglés | MEDLINE | ID: mdl-26799030

RESUMEN

We obtain analytic expressions for the time correlation functions of a liquid of spherical particles, exact in the limit of high dimensions d. The derivation is long but straightforward: a dynamic virial expansion for which only the first two terms survive, followed by a change to generalized spherical coordinates in the dynamic variables leading to saddle-point evaluation of integrals for large d. The problem is, thus, mapped onto a one-dimensional diffusion in a perturbed harmonic potential with colored noise. At high density, an ergodicity-breaking glass transition is found. In this regime, our results agree with thermodynamics, consistently with the general random first order transition scenario. The glass transition density is higher than the best known lower bound for hard sphere packings in large d. Because our calculation is, if not rigorous, elementary, an improvement in the bound for sphere packings in large dimensions is at hand.

4.
J Magn Reson ; 362: 107670, 2024 May.
Artículo en Inglés | MEDLINE | ID: mdl-38603922

RESUMEN

We reveal an interplay between temperature and radical concentration necessary to establish thermal mixing (TM) as an efficient dynamic nuclear polarization (DNP) mechanism. We conducted DNP experiments by hyperpolarizing widely used DNP samples, i.e., sodium pyruvate-1-13C in water/glycerol mixtures at varying nitroxide radical (TEMPOL) concentrations and microwave irradiation frequencies, measuring proton and carbon-13 spin temperatures. Using a cryogen consumption-free prototype-DNP apparatus, we could probe cryogenic temperatures between 1.5 and 6.5 K, i.e., below and above the boiling point of liquid helium. We identify two mechanisms for the breakdown of TM: (i) Anderson type of quantum localization for low radical concentration, or (ii) quantum Zeno localization occurring at high temperature. This observation allowed us to reconcile the recent diverging observations regarding the relevance of TM as a DNP mechanism by proposing a unifying picture and, consequently, to find a trade-off between radical concentration and electron relaxation times, which offers a pathway to improve experimental DNP performance based on TM.

5.
Artículo en Inglés | MEDLINE | ID: mdl-25768570

RESUMEN

Interacting particles confined in a quasi-one-dimensional channel are physical systems which display various equilibrium patterns according to the interparticle interaction and the transverse confinement potential. Depending on the confinement, the particles may be distributed along a straight line, in a staggered row (zigzag), or in a configuration in which the linear and zigzag phases coexist (distorted zigzag). In order to clarify the conditions of existence of each configuration, we have studied the linear stability of the zigzag pattern. We find an acoustic transverse mode that destabilizes the zigzag configuration for short-range interaction potentials, and we calculate the interaction range above which this instability disappears. In particular, we recover the unconditional stability of zigzag patterns for Coulomb interactions. We show that the domain of existence for the distorted zigzag patterns is accurately described by our linear stability analysis. We also emphasize the complexity of finite size effects. Last, we provide a criterion for the onset of instability in the thermodynamic limit and propose a biphasic model that explains some characteristics of the distorted zigzag patterns.


Asunto(s)
Modelos Teóricos , Acústica , Modelos Lineales
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