Decomposing electronic and lattice contributions in optical pump - X-ray probe transient inner-shell absorption spectroscopy of CuO.

Electronic and lattice contributions to picosecond time-resolved X-ray absorption spectra (trXAS) of CuO at the oxygen K-edge are analyzed by comparing trXAS spectra, recorded using excitation wavelengths of 355 nm and 532 nm, to steady-state, temperature-dependent XAS measurements. The trXAS spectra at pump-probe time-delays ≥150 ps are dominated by lattice heating effects. Insight into the temporal evolution of lattice temperature profiles on timescales up to 100s of nanoseconds after laser excitation are reported, on an absolute temperature scale, with a temporal sensitivity and a spatial selectivity on the order of 10s of picoseconds and 10s of nanometers, respectively, effectively establishing an "ultrafast thermometer". In particular, for the 532 nm experiment at ∼5 mJ cm-2 fluence, both the initial sample temperature and its dynamic evolution are well captured by a one-dimensional thermal energy deposition and diffusion model. The thermal conductivity k = (1.3 ± 0.4) W m-1 K-1 derived from this model is in good agreement with the literature value for CuO powder, kpowder = 1.013 W m-1 K-1. For 355 nm excitation, a quantitative analysis of the experiments is hampered by the large temperature gradients within the probed sample volume owing to the small UV penetration depth. The impact of the findings on mitigating or utilizing photoinduced lattice temperature changes in future X-ray free electron laser (XFEL) experiments is discussed.

Crossed-beam slowing to enhance narrow-line ytterbium magneto-optic traps.

We demonstrate a method to enhance the atom loading rate of a ytterbium (Yb) magneto-optic trap (MOT) operating on the 556 nm 1S0 → 3P1 intercombination transition (narrow linewidth Γg = 2π × 182 kHz). Following traditional Zeeman slowing of an atomic beam near the 399 nm 1S0 → 1P1 transition (broad linewidth Γp = 2π × 29 MHz), two laser beams in a crossed-beam geometry, frequency tuned near the same transition, provide additional slowing immediately prior to the MOT. Using this technique, we observe an improvement by a factor of 6 in the atom loading rate of a narrow-line Yb MOT. The relative simplicity and generality of this approach make it readily adoptable to other experiments involving narrow-line MOTs. We also present a numerical simulation of this two-stage slowing process, which shows good agreement with the observed dependence on experimental parameters, and use it to assess potential improvements to the method.