1.
Org Lett
; 6(4): 601-3, 2004 Feb 19.
Artículo
en Inglés
| MEDLINE
| ID: mdl-14961633
RESUMEN
[reaction: see text] Treatment of diphenyl disulfide and terminal alkynes with gallium trichloride afforded (E)-1,2-diphenylthio-1-alkenes selectively (E/Z > 20/1). Alkenes also underwent this reaction to form trans adducts.
2.
Org Biomol Chem
; 3(9): 1622-3, 2005 May 07.
Artículo
en Inglés
| MEDLINE
| ID: mdl-15858641
RESUMEN
Treatment of alpha, beta-unsaturated carbonyl compounds or methyl propargyl ether with acylchlorobis(cyclopentadienyl)titanium in the presence of triethylamine and a copper salt in aqueous THF resulted in acylation of the carbon-carbon multiple bond, yielding the corresponding 1,4-diketones in good yields.