(N-Ethyl-N-phenyl-dithio-carbamato-κS)triphenyl-tin(IV).
Acta Crystallogr Sect E Struct Rep Online
; 68(Pt 1): m62-3, 2012 Jan.
Article
en En
| MEDLINE
| ID: mdl-22259360
The title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NS(2))], has two independent mol-ecules in the asymmetric unit and each features a tetra-hedrally coordinated Sn(IV) atom as the dithio-carbamate ligand coordinates in a monodentate fashion. As the non-coordinating thione S atom is proximate to the Sn atom [Snâ¯S(thione) = 3.1477â
(6) and 2.9970â
(5)â
Å for the independent mol-ecules], distortions from the ideal geometry are evident [the widest angle being 120.48â
(5)°]. The most notable feature of the crystal packing is the formation of C-Hâ¯π inter-actions that lead to the formation of supra-molecular layers parallel to ([Formula: see text]2[Formula: see text]).
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Acta Crystallogr Sect E Struct Rep Online
Año:
2012
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Article