A comprehensive study of the vibrationally resolved S 2p(-1) Auger electron spectrum of carbonyl sulfide.
J Chem Phys
; 137(4): 044310, 2012 Jul 28.
Article
en En
| MEDLINE
| ID: mdl-22852621
ABSTRACT
High-resolution normal Auger-electron spectra of carbonyl sulfide subsequent to S 2p(-1) photoionization at photon energies of 200, 220, and 240 eV are reported along with corresponding photoelectron spectra. In addition, theoretical results are presented that take the core-hole orientation of the various spin-orbit-split and molecular-field-split S 2p(-1) states into account. Auger transitions to eight metastable dicationic final states are observed and assigned on the basis of the theoretical results. From Franck-Condon analysis, assuming Morse potentials along the normal coordinates for seven of the observed quasi-stable dicationic final states, information on the potential-energy surfaces is derived and compared with theoretical results from the literature.
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Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Teoría Cuántica
/
Óxidos de Azufre
Idioma:
En
Revista:
J Chem Phys
Año:
2012
Tipo del documento:
Article
País de afiliación:
Alemania