Tuning the electronic properties of an N-heterocyclic carbene by charge and mesomeric effects.
Chem Commun (Camb)
; 49(47): 5417-9, 2013 Jun 14.
Article
en En
| MEDLINE
| ID: mdl-23652771
ABSTRACT
N-Methylation of a pyridoimidazolium salt and subsequent deprotonation afford a cationic NHC ligand. The spectroscopic characteristics of its Rh and Ir metal complexes reveal the reduced donor and enforced π-acceptor behaviour of this ligand system.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2013
Tipo del documento:
Article
País de afiliación:
Alemania