Excited state investigation of a new Ru(II) complex for dual reactivity with low energy light.
Chem Commun (Camb)
; 51(42): 8777-80, 2015 May 25.
Article
en En
| MEDLINE
| ID: mdl-25912170
ABSTRACT
The new complex [Ru(tpy)(Me2dppn)(py)](2+) efficiently photodissociates py in CH3CN with Φ500 = 0.053(1) induced by steric bulk from methyl substituents and produces (1)O2 with ΦΔ = 0.69(9) from its long-lived (3)ππ* excited state. The unique excited state processes that result in dual reactivity were investigated using ultrafast transient absorption spectroscopy.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Asunto principal:
Teoría Cuántica
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Rutenio
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Complejos de Coordinación
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Luz
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2015
Tipo del documento:
Article
País de afiliación:
Estados Unidos