Conformation driven in situ interlock: from discrete metallocycles to infinite polycatenanes.
Chem Commun (Camb)
; 51(71): 13706-9, 2015 Sep 14.
Article
en En
| MEDLINE
| ID: mdl-26235240
ABSTRACT
A novel conformation driven self-assembly system, where four metallocycles with different conformations have been in situ self-assembled, has been reported. Interestingly, only square metallocycles can further interlock into polycatenanes. However, rectangular and rhombus metallocycles fail to overcome such an entropically unfavourable process, which constitutes an obstacle to the formation of polycatenanes.
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1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2015
Tipo del documento:
Article