Crystal structure of di-µ-chlorido-bis(chlorido-{N (1)-phenyl-N (4)-[(pyridin-2-yl-κN)methyl-idene]benzene-1,4-di-amine-κN (4)}mercury(II)).
Acta Crystallogr E Crystallogr Commun
; 71(Pt 9): m175-6, 2015 Sep 01.
Article
en En
| MEDLINE
| ID: mdl-26396873
ABSTRACT
The whole mol-ecule of the title complex, [Hg2Cl4(C18H15N3)2], is generated by inversion symmetry. It was synthesized from the pyridine-derived Schiff base N-phenyl-N'-[(pyridin-2-yl)methyl-idene]benzene-1,4-di-amine (PPMBD). The five-coordinated Hg(2+) ions have a distorted square-pyramidal environment defined by two N atoms, viz. the imine and the other pyridyl [Hg-N = 2.467â
(6) and 2.310â
(6)â
Å, respectively] belonging to the bidentate imino-pyridine ligand, and three Cl atoms [Hg-Cl = 2.407â
(2), 2.447â
(2) and 3.031â
(2)â
Å]. The longest Hg-Cl bond is bridging about the inversion centre. In the ligand, the central ring and pyridine ring are oriented at a dihedral angle of 8.1â
(4)°, while the planes of the pyridine ring and the terminal phenyl ring are oriented at a dihedral angle of 53.8â
(4)°. In the crystal, mol-ecules are linked by N-Hâ¯Cl and C-Hâ¯Cl hydrogen bonds, forming sheets parallel to (001).
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01-internacional
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MEDLINE
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En
Revista:
Acta Crystallogr E Crystallogr Commun
Año:
2015
Tipo del documento:
Article