Retention of a Four-Fold Interpenetrating Cadmium-Organic Framework through a Three-Step Single Crystal Transformation.
Inorg Chem
; 60(11): 8331-8338, 2021 Jun 07.
Article
en En
| MEDLINE
| ID: mdl-34038101
ABSTRACT
Controlled hydration leads to four derivatives of a metal-organic framework consisting of cadmium ions, N1,N1,N4,N4-tetrakis(4-(pyridin-4-yl)phenyl)benzene-1,4-diamine, and coordinated and free nitrates. The balance of water coordination and the multitude of bonding of the weakly coordinated nitrate lead to a progressive change in the coordination number of the Cd2+ ions from eight to seven to six without great perturbation to the 4-fold interpenetration three-dimensional framework.
Texto completo:
1
Colección:
01-internacional
Banco de datos:
MEDLINE
Idioma:
En
Revista:
Inorg Chem
Año:
2021
Tipo del documento:
Article
País de afiliación:
China