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Stable Radical Isoporphyrin Copolymer Prepared with Di(phenylphosphane).
Liang, Yiming; Bonnefont, Antoine; Badets, Vasilica; Boudon, Corinne; Goldmann, Michel; Diot, Guillaume; Choua, Sylvie; Le Breton, Nolwenn; Ruhlmann, Laurent.
Afiliación
  • Liang Y; Zhengzhou Research Base, National Key Laboratory of Cotton Bio-Breeding and Integrated Utilization, School of Agricultural Sciences, Zhengzhou University, Zhengzhou 450001, China.
  • Bonnefont A; Institut de Chimie, UMR CNRS 7177, Université de Strasbourg, 4 Rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France.
  • Badets V; Institut de Chimie, UMR CNRS 7177, Université de Strasbourg, 4 Rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France.
  • Boudon C; LEPMI, Université 589 Grenoble Alpes, Université Savoie Mont Blanc, CNRS, 590 Grenoble INP, F-38000 Grenoble, France.
  • Goldmann M; Institut de Chimie, UMR CNRS 7177, Université de Strasbourg, 4 Rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France.
  • Diot G; Institut de Chimie, UMR CNRS 7177, Université de Strasbourg, 4 Rue Blaise Pascal, CS 90032, F-67081 Strasbourg Cedex, France.
  • Choua S; Institut des Nanosciences de Paris, UMR CNRS 7588, Sorbonne Université, 4 Place Jussieu, Boîte Courrier 840, F-75252 Paris, France.
  • Le Breton N; UFR des Sciences Fondamentales et Biomédicales, Université Paris-Cité, 45 Rue des Saints Pères, F-75006 Paris, France.
  • Ruhlmann L; Institut des Nanosciences de Paris, UMR CNRS 7588, Sorbonne Université, 4 Place Jussieu, Boîte Courrier 840, F-75252 Paris, France.
Molecules ; 29(13)2024 Jun 27.
Article en En | MEDLINE | ID: mdl-38999012
ABSTRACT
Two diphosphanes with variable-length ligands tested as nucleophiles to prepare isoporphyrin copolymers in the presence of ditolylporphyrin of zinc (ZnT2P) prevented the oxidation of the diphosphine ligand. This paper demonstrates the power of this approach and describes the photoelectrocatalytic properties. The obtained copolymers were characterized by UV-vis spectroscopy, X-ray photoelectron spectroscopy, atomic force micrograph (AFM), EQCM (Electrochemical Quartz Cristal Microbalance) and electrochemistry. Their impedance properties (EIS) were studied and their photovoltaic performances were also investigated by photocurrent transient measurements under visible light irradiation.
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Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2024 Tipo del documento: Article País de afiliación: China
Texto completo
Imprimir
XML
PubMed Links
Buscar en Google

Texto completo: 1 Colección: 01-internacional Banco de datos: MEDLINE Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2024 Tipo del documento: Article País de afiliación: China