External dose measurements to investigate the body-size dependence of personal dosemeter responses in areas affected by the Fukushima Daiichi nuclear accident.

To formulate necessary protective measures after a large-scale nuclear accident, it is crucial to understand the levels of radiation to which persons living in radionuclide-contaminated areas are exposed. Individual monitoring using personal dosemeters (PDs) plays a role in this, although PDs were not originally intended to be used by members of the public. The present study investigated PD responses in areas highly affected by the Fukushima Daiichi nuclear accident, as well as the dependence of those measurements on body size. Three types of commercially available electronic PDs, including D-shuttle, which has often been used in Fukushima, were placed on the front surfaces of three age-specific anthropometric phantoms imitating a 5-y-old, a 10-y-old and an adult male, and these phantoms were then exposed to radiation in an open field in the affected area. In the case of D-shuttle, the ratios of PD readings to the ambient dose rate for the 5-y-old phantom and the adult male phantom were 0.79 and 0.72, respectively. The ratios were somewhat higher for the other PDs; any PDs showed higher readings than the effective doses estimated by simulations based on the assumed ground deposition of 134Cs and/or 137Cs over the affected areas.

Distribution of natural radionuclides in NORM samples from North Abu Rusheid area, Egypt.

The North Abu Rusheid area in Egypt is a well-known high background natural radiation area (HBNRA) due to the existence of naturally occurring radioactive materials (NORMs) in mylonitic rocks. In this study, 27 rock samples were selected for dose estimation studies. 238U and 232Th were measured using inductively coupled plasma mass spectrometry (ICP-MS) and 40K was measured using sodium iodide (thallium) gamma-ray spectroscopy. The ranges of activity concentrations (Bq/kg) of 238U, 232Th and 40K in the samples varied from 270 ± 2 to 2120 ± 29, 350 ± 2 to 1840 ± 27 and 20 ± 2 to 1390 ± 35 with mean values of 980 ± 349, 770 ± 351, and 640 ± 402 Bq/kg, respectively. The radiological hazard parameters were estimated from activity concentrations of 238U, 232Th and 40K and compared to United Nations Scientific Committee on the Effects of Atomic Radiation (UNSCEAR) values. The present study revealed that the hazard parameters were several times higher than the worldwide averages. The U/Th concentration ratio ranged from 0.7 to 3 and could be attributed to the presence of kasolite, uranothorite, zircon, and columbite in mylonitic rocks. From the radiological protection viewpoint, it is necessary to monitor natural radionuclides in these rocks prior to their use in residential and commercial construction materials.

Sorption-desorption coefficients of uranium in contaminated soils collected around Fukushima Daiichi Nuclear Power Station.

Various radionuclides including fission products and heavy nuclides were released into the environment during the Fukushima Daiichi Nuclear Power Station (FDNPS) accident. The dissolution followed by migration of deposited radionuclides of Cs, Sr and U on soils could take place to the local environment. Therefore, it is necessary to determine sorption-desorption coefficients of U in soil-water system around the FDNPS from a migration viewpoint. The determination of sorption coefficient Kd(S) as well as desorption coefficient Kd(D) for U has been carried out in the present study using a laboratory batch method. Stable U was used for sorption from simulated ground water onto contaminated soil samples collected from Okuma Town, Fukushima. Different soil parameters were measured to understand their effects on sorption and desorption processes. The obtained Kd(S) and Kd(D) values of U were compared with values of Kd(S) and Kd(D) of Cs and Sr and Kd(S)-U in known Fukushima accident contaminated soils reported in the literature for better understanding. It was observed that Kd(S)-U varied from 160 to 5100 L/kg, whereas Kd(D)-U ranged from 200 to 11000 L/kg. Kd(D) was higher than Kd(S) for U in these soils implying irreversibility of the sorption process. Pearson's correlation of Kd(S) values suggested that U sorption is affected by various soil parameters. However, desorption is decided by the nature of U species formed in sorption process and soil parameters like pH, presence of carbonates, Ca ions, clay minerals etc. to some extent. The comparison between Kd(S) and Kd(D) values for Cs, Sr and U revealed that unsorbed Sr could migrate farther than unsorbed Cs or U under the present experimental conditions. Both sorption and desorption studies are of great importance to understand migration of metal ions from contaminated sites to local uncontaminated areas.

Geochemical characterization of monazite sands based on rare earth elements, thorium and uranium from a natural high background radiation area in Tamil Nadu, India.

The Kanyakumari coastal area in the southernmost part of Tamil Nadu, India is a well-known natural high background radiation area due to the abundance of monazite in beach placer deposits. In the present study, the concentrations of major oxides, rare earth elements (REEs), Th and U were measured to understand geochemical characteristics of these monazite sands. Based on the ambient dose rate, 23 locations covering an area of about 60 km along the coast were selected for sample collection. The concentrations of U and Th ranged from 1.1 to 737.8 µg g-1 and 25.2-12250.6 µg g-1, respectively. The Th/U ratio ranged from 2.2 to 61.6, which clearly indicated that Th was the dominant contributing radionuclide to the enhanced natural radioactivity in this coastal region. The chondrite-normalized REEs pattern of the placer deposits showed enrichment in light REEs and depletion in heavy REEs with a negative Eu anomaly that indicated the monazite sands were derived from granite, charnockite, and granitoid rocks from the Nagercoil and the Trivandrum Blocks of the Southern Granulite Terrain.

URANIUM, THORIUM AND RARE EARTH ELEMENTS DISTRIBUTION IN FUKUSHIMA SOIL SAMPLES.

Uranium, thorium and rare earth elements (REEs) in soil samples contaminated by Fukushima Dai-ichi Nuclear Power Plant (FDNPP) accident was determined using inductively coupled plasma-mass spectrometry (ICP-MS). This information provides knowledge about concentration levels of REEs in soil samples as a background data after FDNPP accident. Chondrite-normalised REEs pattern does not show enrichment in concentrations of REEs, which could be related to FDNPP accident. The high concentration of these elements at few sampling points may be due to soil formation process from granitic rocks.

NATURAL RADIOACTIVITY MEASUREMENT AND DOSE ASSESSMENT OF BEACH PLACER SANDS IN THE COASTAL REGION OF TAMIL NADU (INDIA).

A preliminary study was carried out to determine the radioactivity concentration of 232Th, 226Ra and 40K in beach placer sands from 13 locations along the coast line of Tamil Nadu state, India. The ambient dose rates varied from 9 to 467 nGy h-1. The activity concentrations of radionuclide 232Th, 226Ra and 40K ranged from 5.2 to 683 Bq kg-1, 13 to 198 Bq kg-1 and 107 to 421 Bq kg-1, respectively. The annual effective dose rate ranges from 27 to 620 µSv y-1 and was higher at seven beaches in comparison to the UNSCEAR annual worldwide average value.

MEASUREMENT OF URANIUM IN URINE, HAIR AND NAILS IN SUBJECTS OF NISKA BANJA TOWN, A HIGH NATURAL BACKGROUND RADIATION AREA OF SERBIA.

Urine, hair and nail samples were collected from a population of both sex aged from 40 to 87 years in Niska Banja (227 km south of Belgrade, Serbia) with a high level of natural radioactivity (HLNRA). To assess and monitor the public exposure, urine samples for each subject (24 h period) were collected and concentration of uranium (U) was analysed using alpha-particle spectrometry. Human hair and nails considered as bio-indicators of the public exposure to radionuclides over a long period of months or even years and concentration of U was determined using inductively coupled plasma-mass spectrometry. The mean concentrations of U in urine, hair and nail were 123 ng/L, 17 ng/g and 8 ng/g, respectively. There was a large variation and may be due to geological origin.

Radiocesium and 40K distribution of river sediments and floodplain deposits in the Fukushima exclusion zone.

In this study, radiocesium and 40K analysis were accomplished for samples of riverbed sediments and floodplain deposits collected from five rivers in the vicinity (<20 km) of the damaged Fukushima Daiichi Nuclear Power Plant after seven years of the accident. Sediment particle size distribution and major oxide content were determined also for six selected samples to understand the retention and migration process of radiocesium in river environments. The radiocesium activity concentration varied from 103 ±â€¯6 Bq·kg-1 to 22,000 ±â€¯500 Bq·kg-1 in riverbed sediments and from 92 ±â€¯5 Bq·kg-1 to 117,000 ±â€¯2000 Bq·kg-1 in floodplain deposits. The 134Cs/137Cs ratio (decay corrected to 15 March 2011) was 1.02 in the both samples. Compared to monitoring results in 2011, it was proved that the radiocesium distribution pattern had been changed remarkably during seven years. The radiocesium was primarily attached to fine clay particles but its sorption on sand and coarse sand particles was also considerable. The sorption process of radiocesium was not affected by the presence of water and moreover, after seven years of the Fukushima accident, a significant radiocesium migration cannot be expected without particle migration. Consequently, radiocesium will remain for a long time in the river environments and its redistribution is mainly affected by the erosion process of the sediments. The average 40K activity concentration of riverbed sediment and floodplain deposit samples was 640 ±â€¯152 Bq·kg-1 changing from 319 ±â€¯18 Bq·kg-1 to 916 ±â€¯41 Bq·kg-1. In the river estuary zones, significant activity concentration decrements were observed for both radionuclides. This suggests that seawater intrusion has a decreasing effect on both natural and artificial radionuclides via wash-out of particulate radiocesium and 40K, and desorption of these radionuclides, but to reveal the detail of this process further investigations are required. The analysis of 40K can help in a simple and easy way to reveal the mineral composition differences of sediment samples.

Variability of radiocaesium inventory in Fukushima soil cores from one site measured at different times.

The Fukushima Daiichi Nuclear Power Plant (FDNPP) accident has resulted in the deposition of radioactive contamination of soils mainly by (134)Cs and (137)Cs. The contaminated areas are of a great concern since external radiation may lead to significant long-term doses to humans and animals. External dose rate above ground will decrease with physical decay of the radionuclides and as they migrate deeper into the soil with time. In the present study, depth profiles of Cs radioisotopes have been studied at different times over a period of 1 y. Radiocaesium inventories for (134)Cs and (137)Cs down to a depth of 10 cm at the four measurement times varied from 2.09 to 4.14 MBq m(-2) with coefficient of variation (CV): 27.4 %, n = 4 and from 2.13 to 4.23 MBq m(-2) with CV: 27.3 %, n = 4, respectively. The activity ratio for (134)Cs/(137)Cs decreased from 0.62 to 0.46 during 1 y of measurement i.e. July 2012 to June 2013. However, the ratio with decay correction (15 March 2011) was found to be constant ∼1, indicating contamination from FDNPP origin. In order to understand the radiocaesium distribution in soil profile, physico-chemical characterisation of soil has been carried out.

Measurement of 90Sr in contaminated Fukushima soils using liquid scintillation counter.

A method based on liquid scintillation counting system has been developed for the measurement of (90)Sr in Fukushima soil samples due to contamination of (134)Cs and (137)Cs. Three soil samples were collected within 30 km radius from the Fukushima Daiichi Nuclear Power Plant (FDNPP). Activity concentration of (134)Cs and (137)Cs were measured using a gamma spectroscopy system with high-purity germanium detector. (90)Sr contamination is little elevated but comparable with the background contamination level that originated from atmospheric nuclear weapon tests, whereas radiocesium contamination has increased significantly. Activity concentration of (90)Sr in the soil samples varied in the range of 10.4±0.6-22.0±1.2 Bq kg(-1). Activity concentrations of (134)Cs and (137)Cs in the soil samples were in the range of 28.2±0.2-56.3±0.2 kBq kg(-1) and 35.2±0.1-70.2±0.2 kBq kg(-1), respectively (reference date for decay correction is 1 December 2011).

Distribution of uranium and some selected trace metals in human scalp hair from Balkans.

The possible consequences of the use of depleted uranium (DU) used in Balkan conflicts in 1995 and 1999 for the people and the environment of this reason need attention. The heavy metal content in human hair may serve as a good indicator of dietary, environmental and occupational exposures to the metal compounds. The present work summarises the distribution of uranium and some selected trace metals such as Mn, Ni, Cu, Zn, Sr, Cd and Cs in the scalp hair of inhabitants from Balkans exposed to DU directly and indirectly, i.e. Han Pijesak, Bratoselce and Gornja Stubla areas. Except U and Cs, all other metals were compared with the worldwide reported values of occupationally unexposed persons. Uranium concentrations show a wide variation ranging from 0.9 ± 0.05 to 449 ± 12 µg kg(-1). Although hair samples were collected from Balkan conflict zones, uranium isotopic measurement ((235)U/(238)U) shows a natural origin rather than DU.

Sorption-desorption characteristics of uranium, cesium and strontium in typical podzol soils from Ukraine.

Sorption-desorption behaviour of uranium (U), cesium (Cs) and strontium (Sr) was examined by quantification of the solid-liquid distribution coefficients (K(d)) using batch method in typical podzol soils from Ukraine. The effect of different physico-chemical parameters of soil on K(d) values has been discussed. Sorption reversibility has been tested by single extraction test. U shows reversible sorption and there was no isotopic fractionation observed with a known isotopic U composition using as tracer. Cs sorption mostly occurred in an irreversible manner. The clay content and exchangeable potassium in soil play an important role in Cs fixation. Sr adsorption is observed to be reversible and mainly controlled by cation exchange and shows highest mobility in the soil-water system. The K(d) values are found in the decreasing order U (log K(d) ≈ 2-3) > Cs (log K(d) ≈ 2) > Sr (log K(d) ≈ 1).

Estimation of dietary 232Th, 238U, cesium, and strontium intakes in Vietnamese people from different geographical regions.

Diet samples were collected to estimate dietary intakes of 232Th, 238U, cesium, and strontium for Vietnamese adults using duplicate portion studies and market basket studies. Average concentrations of 232Th, 238U, cesium, and strontium in diet samples were 4.0 ng/g-dry, 2.5 ng/g-dry, 41 ng/g-dry, and 4.5 ng/g-dry, respectively. Daily intakes per person for 232Th, 238U, cesium, and strontium were estimated to be 0.99 microg, 0.66 microg, 10 microg, and 1.2 mg, respectively. Daily intakes of 232Th, 238U, and cesium differed statistically between northern and southern of Vietnam, depending on geological conditions and food habits. However, intakes of the four nuclides were similar to the global averages.