1.
J Org Chem
; 84(7): 4165-4178, 2019 Apr 05.
Artículo
en Inglés
| MEDLINE
| ID: mdl-30835121
RESUMEN
A AgSCF3/Na2S2O8-promoted trifluoromethylthiolation/cascade cyclization of o-propargyl arylazides (or o-alkynyl benzylazides) triggered by a carbon-carbon triple bond is reported. This strategy provides the synthesis of valuable SCF3-substituted quinoline and isoquinoline systems via the construction of one C(sp2)-SCF3 bond and one C-N bond within one process.