Enhanced sunlight-driven catalysis for hydrogen generation and dye remediation using synergistic p-Co3O4/n-TiO2 nanocomposites.

In this study, p-Co3O4/n-TiO2 nanocomposites were synthesized using different ratios of cobalt and titanium precursors through a hydrothermal method. These nanocomposites demonstrated notable potential in photocatalytic applications for hydrogen production and orange-red dye degradation under sunlight. Various techniques, including XRD, Raman spectroscopy, XPS, FESEM, TEM, and BET analysis, were used to comprehensively characterize their structural, morphological, and optical properties. The nanocomposites exhibited both cubic and tetragonal phases of Co3O4 and TiO2, and their combined effect resulted in a narrowed band gap. Additionally, the presence of Co3O4 induced surface plasmon resonance on the TiO2 surface, effectively impeding electron-hole recombination. The nanocomposites displayed an average particle size of ∼20 to 30 nm with substantial visible light absorption. High crystallinity and well-dispersed nanocomposites were confirmed by XRD and Raman, with BET surface areas ranging between 49 and 106 m2 g-1. Notably, the p-Co3O4/n-TiO2 nanocomposite showed superior photocatalytic activity, achieving a maximum hydrogen generation rate of 1120 µmol h-1 g-1 and an 83% degradation efficiency of the orange-red dye within 6 minutes under sunlight. This study emphasizes the enhanced performance of the p-Co3O4/n-TiO2 nanocomposite, indicating its potential in photocatalytic applications, conforming to a pseudo-first-order kinetics model.

Assessment of ozone toxicity on cotton (Gossypium hirsutum L.) cultivars: Its defensive system and intraspecific sensitivity.

Anthropogenic activities help the ozone formation at the troposphere which causes toxic effects on plants and humans. Ozone is a highly reactive gas that enters in plants through stomata and initiates the overproduction of ROS which causes oxidative stress in plants that lead to the destruction of membranal lipids, proteins, impaired the production of sugars and other metabolites and ultimately damage the cell. Presented study was conducted to assess the ozone toxicity on the biomass accumulation of cotton (Gossypium hirsutum L.) cultivars and the role of antioxidative activity in intraspecific sensitivity among the tested cultivars. Results showed that the ozone exposed plants have higher accumulation of H2O2 and MDA correspond to the EDU supplementation which increase the membrane permeability and adversely influence the protein, starch, and biomass accumulation and allocation of the experimental cotton cultivars. On the basis of biomass reduction, cotton cultivar ADC1 is the most sensitive cultivar, while cultivars G. Cot.21 > GADC-2 and G. Cot.13 is moderately sensitive and cultivar V-797 is the least sensitive to ozone stress. Activated defense mechanism such as enhanced activity of antioxidative compounds and enzymes detoxify the ROS by scavenging H2O2 and protects plants against damage. However, activation of defence is variable among the cultivars and corresponded to the biomass loss. Study concluded that the ozone sensitivity among the cotton cultivars depends on the scavenging of ROS. Further, study recommended cultivar ADC-1 as an assessment tool for ozone and cultivar V-797 for cultivation at ozone prone areas to minimize the agricultural loss.

Ozone risk assessment of castor (Ricinus communis L.) cultivars using open top chamber and ethylenediurea (EDU).

Castor bean (Ricinus communis L.) an important non-edible oilseed crop, is a prominent feed stock towards the generation of renewable materials for industrial production which has multiple applications ranging from cosmetics to biofuels industry. India accounts for 76% of the total world production of castor oil seed. However, major concern for developing countries like India where expanding economy led to rapid increases in gases like NOx, CO and VOCs photochemically form ozone. Ozone is strong oxidant that damages agriculture, ecosystems, and materials with considerable reduction in crop yields and crop quality. One way to reduce ozone induced loss is to focus on the adapting crops to ozone exposure by selecting cultivars with demonstrated ozone resistance. An experiment was conducted for ozone risk assessment of castor cultivars to select cultivar with demonstrated resistance against ozone pollution. This study comprise an open top chamber experiment with three treatments viz. (i) control (ambient ozone concentration), (ii) enhanced ozone (average 75 ppb for 4 h daily throughout the growing season), and (iii) EDU application. Results suggested that the ozone pollution substantially affected growth and physiology of castor cultivars. Crop biomass and yield was also negatively influenced by ozone pollution. Developed defence provided strength to withstand against ozone pollution to the experimental crop cultivars. However, developed defence is cultivar specific and positively correlated with the resistance against ozone pollution. Study concluded that the damage to ozone is directly dependent on the antioxidative potential of plant species. However, ozone adaptability is based on the genetic makeup of the cultivar and yield related loss to ozone can be minimizing by selecting ozone tolerant variety as seen in cultivar Nidhi-999.