RESUMEN
In this study, a simple hydrothermal procedure and in situ precipitation method were used to prepare SnO2-AgBr composites, where the molar ratios of SnO2 and AgBr were 1 : 1, 1 : 2 and 2 : 1. Characterization results showed that the composites had excellent dispersion, crystallinity, and purity. A photocatalytic degradation experiment and first-order kinetic model indicate that SnO2-AgBr (1 : 1) had the best photocatalytic performance, and the degradation rates of 30 mg L-1 simulated MO and MG wastewater reached 96.71% and 93.36%, respectively, in 150 min, which were 3.5 times those of SnO2. The degradation rate of MO and MG increases with the dosage. Humic acid inhibited the degradation of MG, while a low concentration of humic acid promoted the degradation of MO, and the composite has good stability with pH. A free radical trapping experiment shows that ·OH and ·O2- were the main active substances, and h+ was the secondary one. According to the results of the characterization and photocatalysis experiments, a Z-scheme mechanism for the SnO2-AgBr composite was proposed, and the degradation pathway of target pollutants was speculated upon. This study has conceived novel methods for the development of a mature Z-scheme mechanism and in doing so has provided new approaches for the development of photocatalysis for water pollution control.
RESUMEN
A three-dimensional flower-shaped Bi2WO6 has been prepared by a hydrothermal procedure without the addition of an auxiliary agent and under neutral conditions with ultrapure water serving as solvent, and the Ag2S-Bi2WO6 composite with weight ratios of 5, 10, and 15% was prepared by a hydrothermal method. The crystallinity, morphology, mode of binding, and optical properties of the Ag2S-Bi2WO6 composite were characterized, the results of which showed that the composite had excellent dispersion, crystallinity, and purity. The composite with a weight ratio of 10% had the best photocatalytic performance, and the degradation rate of tetracycline reached 95.51% within 120 min, an increase of 27.35% over Bi2WO6. In experiments, some focus was given to the effect of the initial solution pH and the concentrations of humic acid and inorganic anions on the degradation efficiency. Based on free radical capture experiments and the semiconductor theory, the main active substances and mechanisms in the optical catalytic reaction process were studied, and speculation was given concerning the degradation pathway for the target pollutants. This study has conceived novel methods for the development of dual semiconductor systems consisting of a Ag NP composite and in doing so has provided new approaches for the development and photocatalysis for water pollution control.