RESUMEN
In the crystal structure of the title salt, C(8)H(8)NO(2) (+)·I(-), the cations and anions are linked by bifurcated N-Hâ¯(O,I) hydrogen bonds. A near-linear O-Hâ¯I hydrogen bond also exists between the cation and anion, resulting in a two-dimensional network. In the cation, the carboxyl group is twisted with respect to the pyridine ring at a dihedral angle of 15.34â (17)°.
RESUMEN
The title compound, C(8)H(8)N(4), possesses crystallographic mirror symmetry, with four C atoms lying on the reflecting plane, which bis-ects the phenyl and tetra-zole rings. It is composed of a planar r.m.s. deviation (0.0012â Å) tetra-zole ring which is nearly coplanar with the benzene ring, the dihedral angle being 2.67â (9)°. In the crystal, symmetry-related mol-ecules are linked by inter-molecular N-Hâ¯N hydrogen bonds. The mol-ecules stack along [100] with a πâ¯π inter-action involving the phenyl and tetra-zole rings of adjacent mol-ecules [centroid-centroid distance = 3.5639â (15)â Å]. The H atom of the N-H group is disordered over two sites of equal occupancy. The methyl H atoms were modelled as disordered over two sets of sites of equal occupancy rotated by 60° with respect to each other.
RESUMEN
The title compound, C(11)H(11)NO, was synthesized by the reaction of 2-(bromo-meth-yl)benzonitrile and acetyl-acetone in the presence of KOH. In the crystal packing, mol-ecules are linked by inter-molecular N-Hâ¯O hydrogen bonds into chains running parallel to the b axis. Centrosymmetrically-related chains inter-act further through weak C-Hâ¯π inter-actions.