Highly Anisotropic Thermally Conductive Dielectric Polymer/Boron Nitride Nanotube Composites for Directional Heat Dissipation.

An ideal dielectric material for microelectronic devices requires a combination of high anisotropic thermal conductivity and low dielectric constant (ɛ') and loss (tan δ). Polymer composites of boron nitride nanotubes (BNNTs), which offer excellent thermal and dielectric properties, show promise for developing these dielectric polymer composites. Herein, a simple method for fabricating polymer/BNNT composites with high directional thermal conductivity and excellent dielectric properties is presented. The nanocomposites with directionally aligned BNNTs are fabricated through melt-compounding and in situ fibrillation, followed by sintering the fibrous nanocomposites. The fabricated nanocomposites show a significant enhancement in thermal properties, with an in-plane thermal conductivity (K‖) of 1.8 Wm-1K-1-a 450% increase-yielding a high anisotropy ratio (K‖/K⊥) of 36, a 1700% improvement over isotropic samples containing only 7.2 vol% BNNT. These samples exhibit a 120% faster in-plane heat dissipation compared to the through-plane within 2 s. Additionally, they display low ɛ' of ≈3.2 and extremely low tan δ of ≈0.014 at 1 kHz. These results indicate that this method provides a new avenue for designing and creating polymer composites with enhanced directional heat dissipation properties along with high K‖, suitable for thermal management applications in electronic packaging, thermal interface materials, and passive cooling systems.

Mechanical Properties of Injection Molded PP/PET-Nanofibril Composites and Foams.

The creation and application of PET nanofibrils for PP composite reinforcement were studied. PET nanofibrils were fibrillated within a PP matrix using a spunbond process and then injection molded to test for the end-use properties. The nanofibril reinforcement helped to provide higher tensile and flexural performance in solid (unfoamed) injection molded parts. With foam injection molding, the nanofibrils also helped to improve and refine the microcellular morphology, which led to improved performance. Easily and effectively increasing the strength of a polymeric composite is a goal for many research endeavors. By creating nanoscale fibrils within the matrix itself, effective bonding and dispersion have already been achieved, overcoming the common pitfalls of fiber reinforcement. As blends of PP and PET are drawn in a spunbond system, the PET domains are stretched into nanoscale fibrils. By adapting the spunbonded blends for use in injection molding, both solid and foamed nanocomposites are created. The injection molded nanocomposites achieved increased in both tensile and flexural strength. The solid and foamed tensile strength increased by 50 and 100%, respectively. In addition, both the solid and foamed flexural strength increased by 100%. These increases in strength are attributed to effective PET nanofibril reinforcement.

Nanostructure to thermal property relationship of resorcinol formaldehyde aerogels using the fractal technique.

We characterized the morphological features of an organic resorcinol-formaldehyde (RF) aerogel and correlated each feature to the thermal insulation properties. Several RF aerogels were synthesized with different morphological features and structural assemblies. This was done by changing the catalyst percentages and the dilution ratios at the polymerization stage. Then, each morphological feature was assessed and categorized using two scales: the macro scale and the micro scale. We found that the macro-features were independent of the catalyst percentages and depended only on the dilution ratios. By contrast, the micro-features were highly sensitive to any changes during the polymerization process. These changes altered the samples' three main micro-structural factors: (i) the structural assembly, (ii) the porous structure, and (iii) the fractal parameters. Thus, we characterized and quantified each component within these areas. Then, we assessed the structure's heat transfer modes and classified them as follows: (i) solid conductivity through the solid particles, (ii) gas conductivity through the gas molecules, and (iii) thermal radiation. We identified the morphological features in our RF samples and correlated them to each mode of the heat transfer. For example, the samples' solid conductivity was highly dependent on the fractal parameters of our structure; that is, the particles' roughness, the structural complexity, and the structural homogeneity. For those samples with extremely rough particles and a complex structure, the solid conductivity reached the lowest possible point. We also found that the total thermal conductivity was mainly controlled by the micro-morphological features, and that the solid conductivity was the most dominant heat transfer mode.

Ultralow-Threshold and Lightweight Biodegradable Porous PLA/MWCNT with Segregated Conductive Networks for High-Performance Thermal Insulation and Electromagnetic Interference Shielding Applications.

Lightweight, biodegradable, thermally insulating, and electrically conductive materials play a vital role in achieving the sustainable development of our society. The fabrication of such multifunctional materials is currently very challenging. Here, we report a general, facile, and eco-friendly way for the large-scale fabrication of ultralow-threshold and biodegradable porous polylactic acid (PLA)/multiwalled carbon nanotube (MWCNT) for high-performance thermal insulation and electromagnetic interference (EMI) shielding applications. Thanks to the unique structure of the microporous PLA matrix embedded by conductive 3D MWCNT networks, the lightweight porous PLA/MWCNT with a density of 0.045 g/cm3 possesses a percolation threshold of 0.00094 vol %, which, to our knowledge, is the minimum value reported so far. Furthermore, the material exhibits excellent thermal insulation performance with a thermal conductivity of 27.5 mW·m-1·K-1, which is much lower than the best value of common thermal insulation materials. Moreover, it also shows outstanding EMI shielding performance characterized by its high shielding effectiveness (SE) values and absorption-dominated shielding feature. More importantly, its specific EMI SE is as high as 1010 dB·cm3·g-1, which is superior to those of other shielding materials reported so far. Thus, this novel multifunctional material and its general fabrication methodology provide a promising way to meet the growing demand for high-performance multifunctional materials in sustainable development.