Effective Phase Space Representation of the Quantum Dynamics of Vibrational Predissociation of the ArBr2(B,ν =16···25) Complex.

We perform trajectory-based simulations of the vibrational predissociation of the ArBr2(B,ν=16···25) van der Waals triatomic complex, constrained to the T-shape geometry. To this aim, we employ a 2-fold mapping of the quantum dynamics into classical-like dynamics in an extended phase space. The effective phase space comprises two distinct sets of degrees of freedom, namely a collection of coupled harmonic oscillators and an ensemble of quantum trajectories. The time evolution of these variables represent bound and unbound motions of the quantum system, respectively. Quantum trajectories are propagated within the interacting trajectory representation. The comparison between the lifetimes of the predissociating complexes computed using the trajectory-based approach and the experimental results available for the target systems indicates that the present method is competitive with wavepacket propagation techniques. The competition between several simultaneous vibrational relaxation pathways was found to have a direct impact on the time scales of vibrational predissociation. Likewise, the analysis of the time evolution of the trajectories reveals the existence of regions in the effective phase space where transitions to vibrational states of higher energy are more likely to occur. The size and location of these regions influence the transient vibrational distributions and therefore the computed lifetimes. Furthermore, the mechanisms of energy redistribution along the dissociation coordinate are analyzed.

Exciton Spatial Dynamics and Self-Trapping in Carbon Nanocages.

Three-dimensional cage-shaped molecules formed from chainlike structures hold potential as unique optoelectronic materials and host compounds. Their optical, structural, and dynamical features are tunable by changes in shape and size. We perform a comparison of these properties for three sizes of strained conjugated [n.n.n]carbon nanocages composed of three paraphenylene chains (bridges) of length n = 4, 5, or 6. The exciton intramolecular redistribution occurring during nonradiative relaxation has been explored using nonadiabatic excited-state molecular dynamics. Our results provide atomistic insight into the conformational features associated with the observed red- and blue-shift trends in the absorption and fluorescence spectra, respectively, with increasing nanocage size. Their internal conversion processes involve intramolecular energy transfer that leads to exciton self-trapping on a few phenylene units at the center of a single bridge. The dependence of these dynamical features on the size of the nanocage can be used to tune their host-guest chemical properties and their use for organic electronics and catenane-like applications.

Wavepacket golden rule treatment of interparticle Coulombic decay in paired quantum dots.

The interparticle Coulombic decay process in paired quantum dots is studied by electron dynamics calculations. We consider a pair of Coulomb-coupled one-electron charged gallium arsenide quantum dots embedded in a nanowire. The two-electron decay process is approximately described by a single active electron model. Within this model, we employ the time-dependent wavepacket approach to the Fermi golden rule (introduced in the context of vibrational predissociation) to calculate autoionization rates, which are compared to exact rates obtained from fully correlated two-electron dynamics calculations. We found that the approximate decay rates agree well with the exact results in the limit of sufficiently separated quantum dots. Finally, we explore whether the short-range behavior of the new model can be further enhanced by the inclusion of local exchange effects by means of regularization of the Coulomb-potential based on a Jastrow-Slater wavefunction. The proposed method may open a route to study the interparticle Coulombic decay in more intricate systems, e.g., paired metal-nanoparticle-quantum dot systems.

Quasi-Classical Trajectory Study of Atom-Diatomic Molecule Collisions in Symmetric Hyperspherical Coordinates: The F + HCl Reaction as a Test Case.

We investigate the reactive dynamics of the triatomic system F + HCl → HF + Cl for total angular momentum equal zero and for different low-lying rovibrational states of the diatomic molecule. For each of the initial vibrational quantum numbers, the time evolution of the atom-diatom collision process is investigated for a wide range of impact angles and collision energies. To this purpose, the Quasi-Classical Trajectories (QCT) method was implemented in a hyperspherical configuration space. The Hamilton equations of motion are solved numerically in an intermediate effective Cartesian space to exploit the relative simplicity of this intermediate representation. Interatomic interactions are described by a London-Eyring-Polanyi-Sato potential energy surface, specifically developed for the title reaction, and the results of the QCT simulations are discussed in terms of the time-evolution of the hyperangles. The analysis of the collision dynamics using symmetric hyperspherical coordinates provides, in addition to the description in terms of a natural reaction coordinate (the hyperradius), a more striking representation of the exchange dynamics, in terms of the time-dependent probability distribution along the kinematic rotation hyperangle, and a precise distinction between direct and indirect mechanisms of the reaction.

Semiclassical modelling of finite-pulse effects on non-adiabatic photodynamics via initial condition filtering: The predissociation of NaI as a test case.

Femtosecond-laser pulse driven non-adiabatic spectroscopy and dynamics in molecular and condensed phase systems continue to be a challenge for theoretical modelling. One of the main obstacles is the "curse of dimensionality" encountered in non-adiabatic, exact wavepacket propagation. A possible route towards treating complex molecular systems is via semiclassical surface-hopping schemes, in particular if they account not only for non-adiabatic post-excitation dynamics but also for the initial optical excitation. One such approach, based on initial condition filtering, will be put forward in what follows. As a simple test case which can be compared with exact wavepacket dynamics, we investigate the influence of the different parameters determining the shape of a laser pulse (e.g., its finite width and a possible chirp) on the predissociation dynamics of a NaI molecule, upon photoexcitation of the A(0(+)) state. The finite-pulse effects are mapped into the initial conditions for semiclassical surface-hopping simulations. The simulated surface-hopping diabatic populations are in qualitative agreement with the quantum mechanical results, especially concerning the subpicosend photoinduced dynamics, the main deviations being the relative delay of the non-adiabatic transitions in the semiclassical picture. Likewise, these differences in the time-dependent electronic populations calculated via the semiclassical and the quantum methods are found to have a mild influence on the overall probability density distribution. As a result, the branching ratios between the bound and the dissociative reaction channels and the time-evolution of the molecular wavepacket predicted by the semiclassical method agree with those computed using quantum wavepacket propagation. Implications for more challenging molecular systems are given.