1.
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 5): m581-2, 2011 May 01.
Artículo
en Inglés
| MEDLINE
| ID: mdl-21754306
RESUMEN
In the title compound, [Cu(C(6)H(5)O(3))(C(18)H(15)P)(2)]·C(18)H(15)P·CH(3)OH, the pyran-4-one ring is appromimately planar (r.m.s deviation = 0.0138â Å), with the Cu(I) atom 0.451â (5)â Å out of the plane. The Cu(I) atom has a distorted tetra-hedral coordination. The O-Cu-O angle is 80.07â (8)° and the P-Cu-P angle is 123.49â (3)°. The crystal packing is stablized by intra-molecular C-Hâ¯O inter-actions and inter-molecular C-Hâ¯O and O-Hâ¯O inter-actions.