Wastewater stabilisation ponds: Sludge accumulation, technical and financial study on desludging and sludge disposal case studies in France.

Waste stabilisation pond treatment was widely developed during the 1980s in France, where there are now over 3,000 plants. Desludging the ponds has now become essential. In 19 primary facultative ponds, in operation for 12-24 years, the net average sludge accumulation rate was 19 mm/yr. The average per capita accumulation rates ranged from 0.04-0.148 m3/person.year (mean of 0.08 m3/person.year). In primary facultative ponds the volume of sludge represented 15-39% of the total volume of the basin. A filling rate above 30% necessitates desludging. In France, a desludging interval of 15 years is recommended for primary facultative ponds. The cost evaluation of desludging and landspreading showed differences according to the desludging technique used. Desludging after emptying the water had an average cost of 38 Euro/m3 of sludge with 10% dry solid (range from 20 to 83 Euro/m3). Under-water desludging was 50% more expensive. Although desludging is carried out only after several years of operation, its cost must be allowed for in the annual operation and maintenance costs of the process. It can be estimated to be 3 l/person.year. Even with this additional cost, waste stabilisation pond treatment remains less expensive than other treatment processes.

Emission of H2S and mass balance of sulfur in anaerobic ponds.

Anaerobic ponds are highly efficient at removing BOD from wastewater with a reduced land area requirement. However, their use is often limited because of the problem of odor release, primarily due to the emission of hydrogen sulfide (H2S). The experiments were conducted on full scale anaerobic ponds used for the primary treatment of urban wastewater under Mediterranean climatic conditions (south of France). A model was developed to estimate the emission of H2S from water characteristics (temperature, pH and sulfides concentration). The emission rate from anaerobic ponds varied between 20 and 576 mg-S/m2.d, leading to concentrations of H2S in the surrounding atmosphere between 0.2 and 5.2 ppm. These concentrations risked creating odor nuisances for nearby inhabitants. The whole of the results and the analysis of sulfur species in sludge permitted the production of a complete mass balance for sulfur. Methods of reducing the emission of odorous compounds were tested on a large scale. The recirculation of secondary effluent and the use of impermeable or permeable covers appeared to be the most interesting solutions.

Biogas production, sludge accumulation and mass balance of carbon in anaerobic ponds.

This work concerned the application of anaerobic ponds for the primary treatment of urban wastewater in a Mediterranean climate. It was carried out on anaerobic ponds at large scale in Mèze (France). The anaerobic ponds constitute a good primary treatment with the removal of 55% of SS and 30% of BOD5, with a small surface area. The accumulation rate of sludge was only 0.017 m3/capita.year, due to their intensive anaerobic degradation. The anaerobic digestion reached equilibrium after one year of operation. The accumulation of sludge then showed seasonal variations with a substantial accumulation in winter and the digestion of the stock in summer. This change can be related to the influence of the temperature on methanogenesis. The production of biogas (83% CH4) was measured by gas collectors especially developed for this study and was also strongly dependent on temperature. The mass balance of carbon showed that 74% of the removed organic carbon was converted into CH4, 13% into dissolved inorganic carbon and 15% was stored in sludge. However, the anaerobic ponds presented a risk of creating odor nuisances with the emission of H2S.

Influence of load distribution and recycle rate in step-fed facultative ponds.

This study presents the results of research on a wastewater treatment system with four identical facultative ponds in series with step-feeding and recirculation (SFFPR). Four modes of distribution of the influent were studied, which were (in percentages of the inflow per pond): C1 = 25/25/25/25; C2 = 50/20/20/10; C3 = 50/50/0/0; C4 = 100/0/0/0. The organic loading applied to the four ponds overall was around 200 kg BOD5/ha.d. The distribution C4 = 100/0/0/0 was selected for studying the recycle rate. Three recycling rates were studied: 0.5Q, 1Q and 2Q. COD and BOD5 removal efficiencies were high whatever the step-feed distribution. For the distribution C1 and C2, the four ponds were homogeneous. The equal distribution of organic loading rate in C2 distribution was most beneficial for algal growth. For piston pattern distributions (C3 and C4), the ponds receiving the highest loading showed a bacterial biomass higher than that of the primary production. Increasing the recirculation rate seemed to lead towards homogenisation of the ponds, while a decrease appeared to lead to their individualisation and increased their productivity. The SFFPR constitutes a stage of the treatment process which can replace the facultative stage; it produces a high effluent quality and decreases land area requirements.

Odor control of an anaerobic lagoon with a biological cover: floating peat beds.

The use of a biological cover for in situ control of gaseous sulfide emission from an anaerobic pond was investigated by a laboratory-scale experiment. The biological cover, constituting by a peat bed floating on the wastewater, caused a reduction of the H2S emission rate by 84.6%. The addition of Fe3+ (with FeCl3) and plants (Juncus effusus L.) to the peat bed significantly improved the performance to reach a H2S removal of 95.5%. Despite the fluctuations in the sulfide concentration in the wastewater, the performance of the biological covers remained constant during the entire period of the study. The analysis of the different forms of sulfur accumulated in the peat beds allowed the understanding of the mechanisms involved in H2S removal. The high amount of sulfate demonstrated that the conditions were favorable to the biological oxidation of H2S. The addition of Fe3+ increased the formation of insoluble ferrous monosulfide (FeS) and pyrite (FeS2). The plants seemed to convert sulfate into elemental and organic sulfur.