Azadirachta indica leaf extract based green-synthesized ZnO nanoparticles coated on spent tea waste activated carbon for pharmaceuticals and personal care products removal.

Pharmaceuticals and personal care products (PPCPs) are emerging contaminants in aqueous systems, posing threat to both human health and environment. In prior research, predominant focus has been on examining various adsorbents for removing PPCPs from single-pollutant systems. However, no study has delved into simultaneous adsorption of PPCPs multi-pollutant mixture. This study evaluates performance of Azadirachta indica leaf extract-based green-synthesized ZnO nanoparticles coated on spent tea waste activated carbon (ZTAC) for removing sulfadiazine (SZN) and acetaminophen (ACN). Adsorption investigations were conducted in single-component (ACN/SZN) and binary-component (ACN + SZN) systems. The synthesized ZTAC was characterized using SEM, XRD, FTIR, EDX, porosimetry and pHpzc analysis. The study examines impact of time (1-60 min), dose (0.2-4 g/L), pH (2-12) and PPCPs concentration (1-100 mg/L) on ACN and SZN removal. Various kinetic and isotherm models were employed to elucidate mechanisms involved in sorption of PPCPs. Furthermore, synergistic and antagonistic aspects of sorption process in multi-component system were investigated. ZTAC, characterized by its crystalline nature and surface area of 980.85 m2/g, exhibited maximum adsorption capacity of 47.39 mg/g for ACN and 34.01 mg/g for SZN under optimal conditions of 15 min, 3 g/L and pH 7. Langmuir isotherm and pseudo-second-order kinetic model best-fitted the experimental data indicating chemisorption mechanism. Removal of ACN and SZN on ZTAC demonstrated synergistic nature, signifying cooperative adsorption. Overall, valorization of ZTAC offers effective and efficient adsorbent for elimination of PPCPs from wastewater.

Adsorptive removal of pharmaceutically active compounds from multicomponent system using Azadirachta indica induced zinc oxide nanoparticles: analysis of competitive and cooperative adsorption.

In this research, zinc oxide (ZnO) nanoparticles synthesized using neem leaf (Azadirachta indica) extract were used as an adsorbent for removing two widely used pharmaceutical compounds acetaminophen (AMP) and sulfadiazine (SDZ). The synthesized ZnO nanoparticles were characterized using SEM-EDS, FTIR, TEM, BET, and XRD analysis. The synthesized ZnO nanoparticles were found to be in the size range of 10 nm with a surface area of 48.551 m2/g. The adsorptive performance of ZnO nanoparticles in both mono-component (MoS) and multi-component system (MuS) was investigated under various operational parameters viz. contact time, temperature, pH, concentration of pharmaceutical compound and ZnO nanoparticles dose. It was observed that the maximum adsorption capacity of ZnO nanoparticles was 7.87 mg/g and 7.77 mg/g for AMP and SDZ, respectively, under the optimum conditions of 7 pH and 2 g/L adsorbent dosage. The experimental data best-fitted with the pseudo-second-order model and Langmuir model, indicating monolayer chemisorption. Further investigation on removal of AMP and SDZ from multicomponent system was modelled using a Langmuir competitive model. The desorption study has shown 25.28% and 22.4% removal of AMP and SDZ from the surface of ZnO nanoparticles. In general, green synthesized ZnO nanoparticles can be utilized effectively as adsorbent for removal of pharmaceutically active compounds from wastewater.

Competitive adsorption analysis of antibiotics removal from multi-component systems using chemically activated spent tea waste: effect of operational parameters, kinetics, and equilibrium study.

In this study, spent tea powder waste was chemically treated for the synthesis of adsorbent using two activating agents, i.e., sulfuric acid and phosphoric acid, to obtain sulfuric acid activated carbon (SAC) and phosphoric acid activated carbon (PAC). The performance of PAC and SAC for the sorption of tetracycline (TCY) and sulfadiazine (SDZ) antibiotics from mono-component (SDZ/TCY) and multi-component (SDZ + TCY) adsorption systems was investigated. Synergistic and antagonistic effects were studied in removing target pollutants in SDZ + TCY systems. Kinetic and equilibrium studies were modeled by different kinetic and isotherm models. The adsorption capacity was assessed using Langmuir's competitive model in a [Formula: see text]. Pseudo-first-order kinetic and Langmuir isotherm models best fit the experimental kinetic and equilibrium data to remove antibiotics. The Langmuir's maximum adsorption capacity (qm) of PAC for the removal of SDZ and TCY in a [Formula: see text] was found to be 16.75 and 10.87 mg/g, and qm of SAC for the removal of SDZ and TCY was found to be 24.69 and 23.20 mg/g, respectively. In SDZ + TCY multi-component system, adsorption of TCY was synergistic in nature for both PAC and SAC. Sorption of SDZ displayed an antagonistic effect in the SDZ + TCY system for both SAC and PAC. In conclusion, the activated carbons synthesized from spent tea waste could be effectively adopted for the simultaneous adsorption of SDZ and TCY from multi-component systems.