1.
Chem Commun (Camb)
; 60(14): 1896-1899, 2024 Feb 13.
Artículo
en Inglés
| MEDLINE
| ID: mdl-38258882
RESUMEN
The characterization of the triplet state of decatungstate (3DT*) and its NIR phosphorescence with lifetimes â¼100 ns in acetonitrile allow the easy determination of rate constants that are key to understanding its role in catalysis. The absence of oxygen quenching can now be understood as the excitation energy of 3DT* is lower than the energy of singlet oxygen.