RESUMEN
Water incorporated with supramolecular building blocks in organic solvents can play a key role in the circularly polarized luminescence (CPL) inversion and amplification of supramolecular assemblies. Herein, we demonstrate that fine-tuning the water content regulated the assembly structure evolution and made the circular dichroism and CPL sign of the system undergo intriguing inversion, reinversion, and amplification processes based on a unique and interesting glutamide-cyanostilbene system, as supported by morphology, spectroscopic observations, and time-dependent density functional theory calculation.
RESUMEN
In the title compound, C(16)H(15)BrO(3), the dihedral angle between the mean planes of the two benzene rings is 76.64â (2)°. In the crystal structure, there are weak π-π stacking inter-actions, with a centroid-centroid distance of 3.724â (3)â Å, as well as an inter-molecular Câ¯Br distance [3.495â (2)â Å] which is slightly less than the sum of the van der Waals radii for these atoms.