Cross-Modal Graph Semantic Communication Assisted by Generative AI in the Metaverse for 6G.

Recently, the development of the Metaverse has become a frontier spotlight, which is an important demonstration of the integration innovation of advanced technologies in the Internet. Moreover, artificial intelligence (AI) and 6G communications will be widely used in our daily lives. However, the effective interactions with the representations of multimodal data among users via 6G communications is the main challenge in the Metaverse. In this work, we introduce an intelligent cross-modal graph semantic communication approach based on generative AI and 3-dimensional (3D) point clouds to improve the diversity of multimodal representations in the Metaverse. Using a graph neural network, multimodal data can be recorded by key semantic features related to the real scenarios. Then, we compress the semantic features using a graph transformer encoder at the transmitter, which can extract the semantic representations through the cross-modal attention mechanisms. Next, we leverage a graph semantic validation mechanism to guarantee the exactness of the overall data at the receiver. Furthermore, we adopt generative AI to regenerate multimodal data in virtual scenarios. Simultaneously, a novel 3D generative reconstruction network is constructed from the 3D point clouds, which can transfer the data from images to 3D models, and we infer the multimodal data into the 3D models to increase realism in virtual scenarios. Finally, the experiment results demonstrate that cross-modal graph semantic communication, assisted by generative AI, has substantial potential for enhancing user interactions in the 6G communications and Metaverse.

A Robust Pyro-phototronic Route to Markedly Enhanced Photocatalytic Disinfection.

Photocatalysis offers a direct, yet robust, approach to eradicate pathogenic bacteria. However, the practical implementation of photocatalytic disinfection faces a significant challenge due to low-efficiency photogenerated carrier separation and transfer. Here, we present an effective approach to improve photocatalytic disinfection performance by exploiting the pyro-phototronic effect through a synergistic combination of pyroelectric properties and photocatalytic processes. A set of comprehensive studies reveals that the temperature fluctuation-induced pyroelectric field promotes photoexcited carrier separation and transfer and thus facilitates the generation of reactive oxygen species and ultimately enhances photocatalytic disinfection performance. It is worth highlighting that the constructed film demonstrated an exceptional antibacterial efficiency exceeding 95% against pathogenic bacteria under temperature fluctuations and light irradiation. Moreover, the versatile modulation role of the pyro-phototronic effect in boosting photocatalytic disinfection was corroborated. This work paves the way for improving photocatalytic disinfection efficiency by harnessing the synergistic potential of various inherent material properties.

Polar Organic Charge-Transfer Complex of the Asymmetrical Component for Flexible Piezoelectric Energy Harvesting and Self-Powered Wearable Sensors.

Organic piezomaterials have attracted much attention because of their easy processing, lightweight, and mechanic flexibility properties. Developing new smart organic piezomaterials is highly required for new-generation electronic applications. Here, we found a novel organic piezomaterial of organic charge-transfer complex (CTC) consisting of dibenzcarbazole analogue (DBCz) and tetracyanoquinodimethane (TCNQ) in the molecular-level heterojunction stacking mode. The DBCz-TCNQ complex exhibited ferroelectric properties (the saturated polarization of ∼1.23 µC/cm2) at room temperature with a low coercive field. The noncentrosymmetric alignment (Pc space group) led to a spontaneous polarization of this architecture and thus was the origin of the piezoelectric behavior. Lateral piezoelectric nanogenerators (PENGs) based on the thermal evaporated CTC thin-film exhibited significant energy conversion behavior under mechanical agitation with a calculated piezoelectric coefficient (d31) of ∼33 pC/N. Furthermore, such a binary CTC thin-film constructed single-electrode PENG could show steady-state sensing performance to external stimuli as this flexible wearable device precisely detected physiological signals (e.g., finger bending, blink movement, carotid artery, etc.) with a self-powered supply. This work provides that the polar CTCs can act as efficient piezomaterials for flexible energy harvesting, conversion, and wearable sensing devices with a self-powered supply, enabling great potential in healthcare, motion detection, human-machine interfaces, etc.

Stretchable Thermoelectric Fibers with Three-Dimensional Interconnected Porous Network for Low-Grade Body Heat Energy Harvesting.

Electricity generation from body heat has garnered significant interest as a sustainable power source for wearable bioelectronics. In this work, we report stretchable n-type thermoelectric fibers based on the hybrid of Ti3C2Tx MXene nanoflakes and polyurethane (MP) through a wet-spinning process. The proposed fibers are designed with a 3D interconnected porous network to achieve satisfactory electrical conductivity (σ), thermal conductivity (κ), and stretchability simultaneously. We systematically optimize the thermoelectric and mechanical traits of the MP fibers and the MP-60 (with 60 wt % MXene content) exhibits a high σ of 1.25 × 103 S m-1, an n-type Seebeck coefficient of -8.3 µV K-1, and a notably low κ of 0.19 W m-1 K-1. Additionally, the MP-60 fibers possess great stretchability and mechanical strength with a tensile strain of 434% and a breaking stress of 11.8 MPa. Toward practical application, a textile thermoelectric generator is constructed based on the MP-60 fibers and achieves a voltage of 3.6 mV with a temperature gradient between the body skin and ambient environment, highlighting the enormous potential of low-grade body heat energy harvesting.

Nanotherapeutics with immunoregulatory functions for the treatment of bacterial infection.

The advent of drug-resistant pathogens results in the occurrence of stubborn bacterial infections that cannot be treated with traditional antibiotics. Antibacterial immunotherapy by reviving or activating the body's immune system to eliminate pathogenic bacteria has confirmed promising therapeutic strategies in controlling bacterial infections. Subsequent studies found that antimicrobial immunotherapy has its own benefits and limitations, such as avoiding recurrence of infection and autoimmunity-induced side effects. Current studies indicate that the various antibacterial therapeutic strategies inducing immune regulation can achieve superior therapeutic efficacy compared with monotherapy alone. Therefore, summarizing the recent advances in nanomedicine with immunomodulatory functions for combating bacterial infections is necessary. Herein, we briefly introduce the crisis caused by drug-resistant bacteria and the opportunity for antibacterial immunotherapy. Then, immune-involved multimodal antibacterial therapy for the treatment of infectious diseases was systematically summarized. Finally, the prospects and challenges of immune-involved combinational therapy are discussed.

Environment-Responsive Therapeutic Platforms for the Treatment of Implant Infection.

The application of medical implants has greatly improved the survival rate and life quality of patients. Nevertheless, in recent years, there are increasing cases of implant dysfunction or failure because of bacterial infections. Despite significant improvements in biomedicine, there are still serious challenges in the treatment of implant-related infections. With the formation of bacterial biofilms and the development of bacterial resistance, these limitations lead to a low efficacy of conventional antibiotics. To address these challenges, it is urgent to exploit innovative treatment strategies for implant-related infections. Based on these ideas, environment-responsive therapeutic platforms with high selectivity, low drug resistance, and minor dose-limiting toxicity have attracted widespread attention. By using exogenous/endogenous stimuli, the antibacterial activity of therapeutics can be activated on demand and exhibit remarkable therapeutic effects. Exogenous stimuli include photo, magnetism, microwave, and ultrasound. Endogenous stimuli mainly include the pathological characteristics of bacterial infections such as acidic pH, anomalous temperature, and abnormal enzymatic activities. In this review, the recent progress of environment-responsive therapeutic platforms with spatiotemporally controlled drug release/activation is systematically summarized. Afterward, the limitations and opportunities of these emerging platforms are highlighted. Finally, it is hoped that this review will offer novel ideas and techniques to combat implant-related infections.

Recent Advances in Triboelectric Nanogenerators: From Technological Progress to Commercial Applications.

Serious climate changes and energy-related environmental problems are currently critical issues in the world. In order to reduce carbon emissions and save our environment, renewable energy harvesting technologies will serve as a key solution in the near future. Among them, triboelectric nanogenerators (TENGs), which is one of the most promising mechanical energy harvesters by means of contact electrification phenomenon, are explosively developing due to abundant wasting mechanical energy sources and a number of superior advantages in a wide availability and selection of materials, relatively simple device configurations, and low-cost processing. Significant experimental and theoretical efforts have been achieved toward understanding fundamental behaviors and a wide range of demonstrations since its report in 2012. As a result, considerable technological advancement has been exhibited and it advances the timeline of achievement in the proposed roadmap. Now, the technology has reached the stage of prototype development with verification of performance beyond the lab scale environment toward its commercialization. In this review, distinguished authors in the world worked together to summarize the state of the art in theory, materials, devices, systems, circuits, and applications in TENG fields. The great research achievements of researchers in this field around the world over the past decade are expected to play a major role in coming to fruition of unexpectedly accelerated technological advances over the next decade.

Multilevel resistive switching in stable all-inorganic n-i-p double perovskite memristor.

Memristors are promising information storage devices for commercial applications because of their long endurance and low power consumption. Particularly, perovskite memristors have revealed excellent resistive switching (RS) properties owing to the fast ion migration and solution fabrication process. Here, an n-i-p type double perovskite memristor with "ITO/SnO2/Cs2AgBiBr6/NiOx/Ag" architecture was developed and demonstrated to reveal three resistance states because of the p-n junction electric field coupled with ion migration. The devices exhibited reliable filamentary with an on/off ratio exceeding 50. The RS characteristics remained unchanged after 1000 s read and 300 switching cycles. The synaptic functions were examined through long-term depression and potentiation measurements. Significantly, the device still worked after one year to reveal long-term stability because of the all-inorganic layers. This work indicates a novel idea for designing a multistate memristor by utilizing the p-n junction unidirectional conductivity during the forward and reverse scanning.

Recent Advances in Efficient Photocatalysis via Modulation of Electric and Magnetic Fields and Reactive Phase Control.

The past several years has witnessed significant progress in enhancing photocatalytic performance via robust electric and magnetic fields' modulation to promote the separation and transfer of photoexcited carriers, and phase control at reactive interface to lower photocatalytic reaction energy barrier and facilitate mass transfer. These three research directions have received soaring attention in photocatalytic field. Herein, recent advances in photocatalysis modulated by electric field (i.e., piezoelectric, pyroelectric, and triboelectric fields, as well as their coupling) with specific examples and mechanisms discussion are first examined. Subsequently, the strategy via magnetic field manipulation for enhancing photocatalytic performance is scrutinized, including the spin polarization, Lorentz force, and magnetoresistance effect. Afterward, materials with tailored structure and composition design enabled by reactive phase control and their applications in photocatalytic hydrogen evolution and carbon dioxide reduction are reviewed. Finally, the challenges and potential opportunities to further boost photocatalytic efficiency are presented, aiming at providing crucial theoretical and experimental guidance for those working in photocatalysis, ferroelectrics, triboelectrics, piezo-/pyro-/tribo-phototronics, and electromagnetics, among other related areas.

Stimuli-responsive therapeutic systems for the treatment of diabetic infected wounds.

Diabetic wound infection is a common disease that has significantly reduced people's quality of life. Although tremendous achievements have been made in clinical treatment, the crucial challenge in diabetic infected wound management stems from the detrimental diabetic wound environment and the emergence of bacterial resistance after long-term medication, which result in a reduced efficacy, an increased dosage of medication, and severe side effects. To tackle these issues, it is of great significance to develop an innovative treatment strategy for diabetic wound infection therapy. Currently, the exploitation of nanobiomaterial-based therapeutic systems for diabetic infected wounds is booming, and therapeutic systems with a stimuli-responsive performance have received extensive attention. These therapeutic systems are able to accelerate diabetic infected wound healing due to the on-demand release of therapeutic agents in diabetic infected wounds in response to stimulating factors. Based on the characteristics of diabetic infected wounds, many endogenous stimuli-responsive (e.g., glucose, enzyme, hypoxia, and acidity) therapeutic systems have been employed for the targeted treatment of infected wounds in diabetic patients. Additionally, exogenous stimulants, including light, magnetism, and temperature, are also capable of achieving on-demand drug release and activation. In this review, the characteristics of diabetic infected wounds are presented, and then exogenous/endogenous stimuli therapeutic systems for the treatment of diabetic infected wounds are summarized. Finally, the current challenges and future outlook of stimuli-responsive therapeutic systems are also discussed.

Fluid Field Modulation in Mass Transfer for Efficient Photocatalysis.

Mass transfer is an essential factor determining photocatalytic performance, which can be modulated by fluid field via manipulating the kinetic characteristics of photocatalysts and photocatalytic intermediates. Past decades have witnessed the efforts and achievements made in manipulating mass transfer based on photocatalyst structure and composition design, and thus, a critical survey that scrutinizes the recent progress in this topic is urgently necessitated. This review examines the basic principles of how mass transfer behavior impacts photocatalytic activity accompanying with the discussion on theoretical simulation calculation including fluid flow speed and pattern. Meanwhile, newly emerged viable photocatalytic micro/nanomotors with self-thermophoresis, self-diffusiophoresis, and bubble-propulsion mechanisms as well as magnet-actuated photocatalytic artificial cilia for facilitating mass transfer will be covered. Furthermore, their applications in photocatalytic hydrogen evolution, carbon dioxide reduction, organic pollution degradation, bacteria disinfection and so forth are scrutinized. Finally, a brief summary and future outlook are presented, providing a viable guideline to those working in photocatalysis, mass transfer, and other related fields.

Self-Powered Electrodeposition System for Sub-10-nm Silver Nanoparticles with High-Efficiency Antibacterial Activity.

Recently, silver nanoparticles (AgNPs) have been widely applied in sterilization due to their excellent antibacterial properties. However, AgNPs require rigorous storage conditions because their antibacterial performances are significantly affected by environmental conditions. Instant fabrication provides a remedy for this drawback. In this study, we propose a self-powered electrodeposition system to synthesize sub-10-nm AgNPs, consisting of a triboelectric nanogenerator (TENG) as the self-powered source, a capacitor for storing electrical energy from the TENG, and an electrochemical component for electrodeposition. The self-powered system with larger capacitance and discharging voltage tends to deliver smaller AgNPs due to the nucleation mechanism dominated by current density. Furthermore, antibacterial tests reveal that compared to direct current (DC) electrodeposition, the TENG-based electrodeposition can synthesize finer-sized AgNPs (<10 nm) with overwhelming antibacterial effect against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) (with 100% efficiency at 2 h). This work provides a new strategy for the self-powered, instant, and controllable electrodeposition of nanoparticles.

An Automated Power Evaluation Workbench for Triboelectric Nanogenerators.

Triboelectric nanogenerators (TENGs) have high potential in self-powered sensing and energy harvesting applications. In general, TENGs' internal source resistance is high, and their output power varies under different load resistance values. Therefore, a resistance box is required to evaluate their energy harvesting performance and obtain the power curve under different load values. The load tuning process is usually performed by hand. This repetitive process is time-consuming and error-prone. Consequently, an Automated Power Evaluation Workbench (APEW) is developed, making the resistance switching and power measuring process program-controlled. The resistance value is resolved using the Octal decomposition principle. In addition, a resistance synthesis algorithm is proposed to alter the resistance value with a minimum step of 1 Ohm. The target resistance value is physically synthesized by relay switching, while digital lines control the relays. The proposed APEW is then evaluated experimentally, and the obtained results are compared with those of the traditional manual switching approach. It is deduced that the two power curves are almost identical. Therefore, it is believed that the proposed APEW will play a crucial role in TENG's further development.

Beyond the Pore Size Limitation of a Nanoporous Graphene Monolayer Membrane for Water Desalination Assisted by an External Electric Field.

One efficient strategy for addressing the global water shortage is advanced membrane separation, which depends on the precise pore size being close to the hydrated ion size and other surface properties like charge and polarity. However, it is very difficult to fabricate uniform pores with diameters of <1 nm on monolayer membranes. By applying an electric field (bias voltage) perpendicular to the direction of the pressure difference, herein we demonstrate for the first time that a monolayer nanoporous graphene membrane with pores much larger than hydrated ions exhibits high salt rejection and allows a high rate of water transport. This theoretical proposal goes beyond the pore size limitation and shows promise for the design of high-performance reverse osmosis membranes.

A portable triboelectric spirometer for wireless pulmonary function monitoring.

Coronavirus disease 2019 (COVID-19) as a severe acute respiratory syndrome infection has spread rapidly across the world since its emergence in 2019 and drastically altered our way of life. Patients who have recovered from COVID-19 may still face persisting respiratory damage from the virus, necessitating long-term supervision after discharge to closely assess pulmonary function during rehabilitation. Therefore, developing portable spirometers for pulmonary function tests is of great significance for convenient home-based monitoring during recovery. Here, we propose a wireless, portable pulmonary function monitor for rehabilitation care after COVID-19. It is composed of a breath-to-electrical (BTE) sensor, a signal processing circuit, and a Bluetooth communication unit. The BTE sensor, with a compact size and light weight of 2.5 cm3 and 1.8 g respectively, is capable of converting respiratory biomechanical motions into considerable electrical signals. The output signal stability is greater than 93% under 35%-81% humidity, which allows for ideal expiration airflow sensing. Through a wireless communication circuit system, the signals can be received by a mobile terminal and processed into important physiological parameters, such as forced expiratory volume in 1 s (FEV1) and forced vital capacity (FVC). The FEV1/FVC ratio is then calculated to further evaluate pulmonary function of testers. Through these measurement methods, the acquired pulmonary function parameters are shown to exhibit high accuracy (>97%) in comparison to a commercial spirometer. The practical design of the self-powered flow spirometer presents a low-cost and convenient method for pulmonary function monitoring during rehabilitation from COVID-19.

Selectivity of ion transport in narrow carbon nanotubes depends on the driving force due to drag or drive nature of their active hydration shells.

Molecular dynamics simulations have revealed the important roles of hydration shells of ions transported through ultrathin carbon nanotubes (CNTs). In particular, ions driven by electric fields tend to drag their hydration shells behind them, while for ions transported by pressure, their hydration shells can actively drive them. Given the different binding strengths of hydration shells to ions of different sizes, these active roles of hydration shells affect the relative entry rates and driving speeds of ions in CNTs.

Stretchable and Wearable Triboelectric Nanogenerator Based on Kinesio Tape for Self-Powered Human Motion Sensing.

Recently, wearable, self-powered, active human motion sensors have attracted a great deal of attention for biomechanics, physiology, kinesiology, and entertainment. Although some progress has been achieved, new types of stretchable and wearable devices are urgently required to promote the practical application. In this article, targeted at self-powered active human motion sensing, a stretchable, flexible, and wearable triboelectric nanogenerator based on kinesio tapes (KT-TENG) haven been designed and investigated systematically. The device can effectively work during stretching or bending. Both the short-circuit transferred charge and open-circuit voltage exhibit an excellent linear relationship with the stretched displacements and bending angles, enabling its application as a wearable self-powered sensor for real-time human motion monitoring, like knee joint bending and human gestures. Moreover, the KT-TENG shows good stability and durability for long-term operation. Compared with the previous works, the KT-TENG without a macro-scale air gap inside, or stretchable triboelectric layers, possesses various advantages, such as simple fabrication, compact structure, superior flexibility and stability, excellent conformable contact with skin, and wide-range selection of triboelectric materials. This work provides a new prospect for a wearable, self-powered, active human motion sensor and has numerous potential applications in the fields of healthcare monitoring, human-machine interfacing, and prosthesis developing.

Self-powered thin-film motion vector sensor.

Harnessing random micromeso-scale ambient energy is not only clean and sustainable, but it also enables self-powered sensors and devices to be realized. Here we report a robust and self-powered kinematic vector sensor fabricated using highly pliable organic films that can be bent to spread over curved and uneven surfaces. The device derives its operational energy from a close-proximity triboelectrification of two surfaces: a polytetrafluoroethylene film coated with a two-column array of copper electrodes that constitutes the mover and a polyimide film with the top and bottom surfaces coated with a two-column aligned array of copper electrodes that comprises the stator. During relative reciprocations, the electrodes in the mover generate electric signals of ±5 V to attain a peak power density of ≥65 mW m(-2) at a speed of 0.3 ms(-1). From our 86,000 sliding motion tests of kinematic measurements, the sensor exhibits excellent stability, repeatability and strong signal durability.

Robust triboelectric nanogenerator based on rolling electrification and electrostatic induction at an instantaneous energy conversion efficiency of ∼ 55%.

In comparison to in-pane sliding friction, rolling friction not only is likely to consume less mechanical energy but also presents high robustness with minimized wearing of materials. In this work, we introduce a highly efficient approach for harvesting mechanical energy based on rolling electrification and electrostatic induction, aiming at improving the energy conversion efficiency and device durability. The rolling triboelectric nanogenerator is composed of multiple steel rods sandwiched by two fluorinated ethylene propylene (FEP) thin films. The rolling motion of the steel rods between the FEP thin films introduces triboelectric charges on both surfaces and leads to the change of potential difference between each pair of electrodes on back of the FEP layer, which drives the electrons to flow in the external load. As power generators, each pair of output terminals works independently and delivers an open-circuit voltage of 425 V, and a short-circuit current density of 5 mA/m(2). The two output terminals can also be integrated to achieve an overall power density of up to 1.6 W/m(2). The impacts of variable structural factors were investigated for optimization of the output performance, and other prototypes based on rolling balls were developed to accommodate different types of mechanical energy sources. Owing to the low frictional coefficient of the rolling motion, an instantaneous energy conversion efficiency of up to 55% was demonstrated and the high durability of the device was confirmed. This work presents a substantial advancement of the triboelectric nanogenerators toward large-scope energy harvesting and self-powered systems.