Your browser doesn't support javascript.
loading
Mostrar: 20 | 50 | 100
Resultados 1 - 20 de 68
Filtrar
Más filtros

País/Región como asunto
Tipo del documento
Intervalo de año de publicación
1.
Comput Biol Med ; 181: 109053, 2024 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-39217964

RESUMEN

Giant intracerebral aneurysms (GIA) comprise up to 5 % of all intracranial aneurysms. The indirect surgical strategy, which leaves the GIA untouched but reverses the blood flow by performing a bypass in combination with proximal parent artery occlusion is a useful method to achieve spontaneous aneurysm occlusion. The goal of this study was to assess the utility of computational fluid dynamics (CFD) in preoperative GIA treatment planning. We hypothesise that CFD simulations will predict treatment results. A fluid-structure interaction (FSI) CFD investigation was performed for the entire arterial brain circulation. The analyses were performed in three patient-specific CT angiogram models. The first served as the reference geometry with a C6 internal carotid artery (ICA) GIA, the second a proximal parent artery occlusion (PAO) and virtual bypass to the frontal M2 branch of the middle cerebral artery (MCA), and the third a proximal PAO in combination with a temporal M2 branch bypass. The volume of "old blood", flow residence time (FRT), dynamic viscosity and haemodynamic changes were also analysed. The "old blood" within the aneurysm in the bypass models reached 41 % after 20 cardiac cycles while in the reference model it was fully washed out. In Bypass 2 "old blood" was also observed in the main trunk of the MCA after 20 cardiac cycles. Extrapolation of the results yielded a duration of 4 years required to replace the "old blood" inside the aneurysm after bypass revascularization. In both bypass models a 7-fold increase in mean blood viscosity in the aneurysm region was noted. Bypass revascularization combined with proximal PAO favours thrombosis. Areas prone to thrombus formation, and subsequently the treatment outcomes, were accurately identified in the preoperative model. Virtual surgical operations can give a remarkable insight into haemodynamics that could support operative decision-making.


Asunto(s)
Aneurisma Intracraneal , Humanos , Aneurisma Intracraneal/fisiopatología , Aneurisma Intracraneal/cirugía , Aneurisma Intracraneal/diagnóstico por imagen , Modelos Cardiovasculares , Hidrodinámica , Simulación por Computador , Hemodinámica/fisiología , Circulación Cerebrovascular/fisiología , Masculino
2.
Nanomaterials (Basel) ; 14(15)2024 Aug 03.
Artículo en Inglés | MEDLINE | ID: mdl-39120413

RESUMEN

As an environmentally friendly material, biochar is increasingly being utilized in the field of heat transfer and thermal conduction. In this study, nano-biochar was prepared from high-pressure homogenization (HPH) using sesame stalks as the raw material. It was incorporated into ethylene glycol (EG) and its dispersion stability, viscosity, and thermal conductivity were investigated. The nano-biochar was stably dispersed in EG for 28 days. When the concentration of the nano-biochar added to EG was less than 1%, the impact on viscosity was negligible. The addition of 5 wt.% nano-biochar to EG improved the thermal conductivity by 6.72%, which could be attributed to the graphitized structure and Brownian motion of the nano-biochar. Overall, nano-biochar has the potential to be applied in automotive thermal management.

3.
Int Ophthalmol ; 44(1): 171, 2024 Apr 08.
Artículo en Inglés | MEDLINE | ID: mdl-38587686

RESUMEN

PURPOSE: To assess the dynamic viscosity of the lacrimal sac wall in patients with various origins of lacrimal duct obstruction. METHODS: The study was performed in 35 cases: 21 cases with primary nasolacrimal duct obstruction (PANDO) and 14 cases with secondary nasolacrimal duct obstruction after radioiodine therapy (SALDO). The study of biomechanical properties of the lacrimal sac was carried out using a test bench. The principle of the study was to indent the sample at a given speed and record the data obtained from the sensor of the force transmitted to the sample. The area under the curve (AUC) and the peak viscosity were calculated. A qualitative characteristic of the obtained curve was given. RESULTS: Median AUC in patients with PANDO was 17 × 106 [6 × 106; 19 × 106] N/m2 × s, in patients with SALDO 21 × 106 [13 × 106; 25 × 106] N/m2 × s. Intergroup differences were statistically significant (p = 0,048). The median peak viscosity in PANDO patients was 29 × 106 [25 × 106; 35 × 106] N/m2, in patients with SALDO 32 × 106 [21 × 106; 41 × 106] N/m2. The qualitative characteristics of the obtained curves differed. CONCLUSION: Biomechanical properties of the lacrimal sac may vary depending on the cause of obliteration of the lacrimal ducts. The integrated dynamic viscosity is significantly higher in SALDO patients due to exposure to radioiodine compared to that in PANDO patients.


Asunto(s)
Aparato Lagrimal , Obstrucción del Conducto Lagrimal , Conducto Nasolagrimal , Humanos , Obstrucción del Conducto Lagrimal/diagnóstico , Radioisótopos de Yodo , Viscosidad
4.
Polymers (Basel) ; 16(3)2024 Jan 30.
Artículo en Inglés | MEDLINE | ID: mdl-38337265

RESUMEN

Infections of agricultural crops caused by pathogen ic fungi are among the most widespread and harmful, as they not only reduce the quantity of the harvest but also significantly deteriorate its quality. This study aims to develop unique seed-coating formulations incorporating biopolymers (polyhydroxyalkanoate and pullulan) and beneficial microorganisms for plant protection against phytopathogens. A microbial association of biocompatible endophytic bacteria has been created, including Pseudomonas flavescens D5, Bacillus aerophilus A2, Serratia proteamaculans B5, and Pseudomonas putida D7. These strains exhibited agronomically valuable properties: synthesis of the phytohormone IAA (from 45.2 to 69.2 µg mL-1), antagonistic activity against Fusarium oxysporum and Fusarium solani (growth inhibition zones from 1.8 to 3.0 cm), halotolerance (5-15% NaCl), and PHA production (2.77-4.54 g L-1). A pullulan synthesized by Aureobasidium pullulans C7 showed a low viscosity rate (from 395 Pa·s to 598 Pa·s) depending on the concentration of polysaccharide solutions. Therefore, at 8.0%, w/v concentration, viscosity virtually remained unchanged with increasing shear rate, indicating that it exhibits Newtonian flow behavior. The effectiveness of various antifungal seed coating formulations has been demonstrated to enhance the tolerance of barley plants to phytopathogens.

5.
Heliyon ; 9(10): e21113, 2023 Oct.
Artículo en Inglés | MEDLINE | ID: mdl-37886762

RESUMEN

In general, A nanofluid is a substance in which solids and fluids are mixed. The nano-powder of zirconium oxide (ZrO2) and silicon carbide (SiC) was dispersed into the distilled water (DW) using the widely adopted two-step technique. A Brookfield viscometer was used to measure the viscosity of the nanoparticles of ZrO2/DW and SiC/DW, where the temperature ranged between 20 and 60 °C and different solid volume fractions of 0.025, 0.05, 0.075, and 0.1 % were used. An examination of the mono nanofluids of ZrO2/DW and SiC/DW was conducted to assess their rheological behaviour. The findings of the experiments revealed that the Newtonian behaviour did not change when the nano-powder was added. Increasing the solid volume fraction of the nanoparticles and lowering the temperature resulted in the sample's dynamic viscosity being augmented. Hence, as the temperature rose, nanoparticles had a more observable impact on the viscosity. Furthermore, the findings showed that the increase in the ZrO2/DW nanofluid's viscosity peaked at 226.3 %, whereas for the SiC/DW nanofluid, it was 110.5 %. Additionally, according to the results of the experiments, new correlations capable of predicting the investigated nanofluids' viscosity in relation to solid concentration and temperature has been suggested. The study's results could motivate expanded utilization of nanofluids by researchers working on energy applications.

6.
Materials (Basel) ; 16(18)2023 Sep 16.
Artículo en Inglés | MEDLINE | ID: mdl-37763523

RESUMEN

This paper describes an investigation of the effects of silicone-containing additives on the tribological and rheological properties of various lubricant blends. Aerosil® and layered silicate were used to modify lubricants containing rapeseed, linseed and soy oil that were thickened with soap thickener. Tribological tests were carried out using a four-ball concentric contact tester. On the basis of the data obtained from the tribological studies of the selected lubricant blends, it was concluded that the addition of amorphous silica increased the anti-seizure and anti-wear properties of the tested lubricants. The addition of montmorillonite caused a significant increase in the values of the individual parameters determining the level of lubricating properties of the tested lubricants in comparison with the lubricants modified with the silica additive. Based on the results of the rheological tests of the studied lubricants, it was found that the applied additives caused a change in the dynamic viscosity and chemical structure of the tested lubricants, expressed by a change in the values of the G' and G″ indices. The main finding of this manuscript was to demonstrate that the use of montmorillonite and aerosil additives improves the functional properties of vegetable-based plastic lubricants. The performance of tribological and rheological tests is of great scientific importance, as it provides an insight into the interaction of siliceous additives with the results of tribological tests on vegetable-oil-based greases. These findings make it possible to determine the behaviour of the lubricant under load and add to the knowledge of vegetable greases.

7.
Nanomaterials (Basel) ; 13(16)2023 Aug 11.
Artículo en Inglés | MEDLINE | ID: mdl-37630897

RESUMEN

Microemulsions are nanocolloidal systems composed of water, an oil, and a surfactant, sometimes with an additional co-surfactant, which have found a wide range of practical applications, including the extractive removal of contaminants from polluted water. In this study, microemulsion systems, including a nonionic surfactant (Brij 30), water, and esters selected from two homologous series of C1-C6 alkyl acetates and ethyl C1-C4 carboxylates, respectively, were prepared by the surfactant titration method. Phase transitions leading to the formation of Winsor II and Winsor IV microemulsions were observed and phase diagrams were constructed. The dependences of phase transitions on the salinity and pH and the addition of isopropanol as a co-surfactant were also investigated. Some physical properties, namely density, refractive index, electrical conductivity, dynamic viscosity, and particle size, were measured for a selection of Winsor IV microemulsions, providing further insight into some other phase transitions occurring in the monophasic domains of phase diagrams. Finally, Winsor II microemulsions were tested as extraction solvents for the removal of four tricyclic antidepressant drugs from aqueous media. Propyl acetate/Brij 30/H2O microemulsions provided the best extraction yields (>90%), the highest Nernst distribution coefficients (~40-88), and a large volumetric ratio of almost 3 between the recovered purified water and the resulting microemulsion extract. Increasing the ionic strength (salinity) or the pH of the aqueous antidepressant solutions led to an improvement in extraction efficiencies, approaching 100%. These results could be extrapolated to other classes of pharmaceutical contaminants and suggest ester- and nonionic surfactant-based microemulsions are a promising tool for environmental remediation.

8.
Materials (Basel) ; 16(15)2023 Jul 31.
Artículo en Inglés | MEDLINE | ID: mdl-37570094

RESUMEN

The paper determines the properties of geopolymer pastes based on metakaolin and soda-lime waste glass. The density, alkaline activity, strength and microstructure of the reference geopolymer, as well as geopolymers with a 10%, 30% and 50% soda-lime waste glass content instead of metakaolin, were tested. The experimental results indicate that the properties of the geopolymers with waste glass largely depend on the ratio of the liquid to solid substance. Increasing the content of waste glass causes an increase in the fluidity of the geopolymer paste, which in turn allows the amount of water glass, i.e., an activator during the obtaining of geopolymers, to be reduced. On the basis of the conducted tests, it was found that the strength of geopolymers can be increased by adding up to 50% of soda-lime waste glass instead of metakaolin and by having a lower content of water glass.

9.
Sensors (Basel) ; 23(14)2023 Jul 16.
Artículo en Inglés | MEDLINE | ID: mdl-37514734

RESUMEN

Mineral oil (MO) is the most popular insulating liquid that is used as an insulating and cooling medium in electrical power transformers. Indeed, for green energy and environmental protection requirements, many researchers introduced other oil types to study the various characteristics of alternative insulating oils using advanced diagnostic tools. In this regard, natural ester oil (NEO) can be considered an attractive substitute for MO. Although NEO has a high viscosity and high dielectric loss, it presents fire safety and environmental advantages over mineral oil. Therefore, the retrofilling of aged MO with fresh NEO is highly recommended for power transformers from an environmental viewpoint. In this study, two accelerated aging processes were applied to MO for 6 and 12 days to simulate MO in service for 6 and 12 years. Moreover, these aged oils were mixed with 80% and 90% fresh NEO. The dielectric strength, relative permittivity, and dissipation factor were sensed using a LCR meter and oil tester devices for all prepared samples to support the condition assessment performance of the oil mixtures. In addition, the electric field distribution was analyzed for a power transformer using the oil mixtures. Furthermore, the dynamic viscosity was measured for all insulating oil samples at different temperatures. From the obtained results, the sample obtained by mixing 90% natural ester oil with 10% mineral oil aged for 6 days is considered superior and achieves an improvement in dielectric strength and relative permittivity by approximately 43% and 48%, respectively, compared to fresh mineral oil. However, the dissipation factor was increased by approximately 20% but was at an acceptable limit. On the other hand, for the same oil sample, due to the higher molecular weight of the NEO, the viscosities of all mixtures were at a higher level than the mineral oil.

10.
Heliyon ; 9(6): e16716, 2023 Jun.
Artículo en Inglés | MEDLINE | ID: mdl-37292319

RESUMEN

This study focuses on predicting the dynamic viscosity of nanofluids, specifically Polyalpha-Olefin-hexagonal boron nitride (PAO-hBN) using machine learning models. The primary goal of this research is to assess and contrast the effectiveness of three distinct machine learning models: Support Vector Regression (SVR), Artificial Neural Networks (ANN), and Adaptive Neuro-Fuzzy Inference System (ANFIS). The main objective is the identification of a model that demonstrates the highest level of accuracy in predicting a nanofluid's viscosity namely, PAO-hBN nanofluids. The models were trained and validated using 540 experimental data points, where the mean square error (MSE) and the coefficient of determination R2 were utilized for performance evaluation. The results demonstrated that all three models could predict the viscosity of PAO-hBN nanofluids accurately, but the ANFIS and ANN models outperformed the SVR model. The ANFIS and ANN models had similar performance, but the ANN model was preferred due to its faster training and computation time. The optimized ANN model had an R2 of 0.99994, which indicates a high level of accuracy in predicting the viscosity of PAO-hBN nanofluids. The elimination of the shear rate parameter from the input layer improved the accuracy of the ANN model to an absolute relative error of less than 1.89% over the full temperature range (-19.7 °C-70 °C) compared to 11% in the traditional correlation-based model. These results suggest that the use of machine learning models can significantly improve the accuracy of predicting the viscosity of PAO-hBN nanofluids. Overall, this study demonstrated that the use of machine learning models, specifically ANN, can be effective in predicting PAO-hBN nanofluids' dynamic viscosity. The findings provide a new perspective on how to predict the thermodynamic properties of nanofluids with high accuracy, which could have important applications in various industries.

11.
Foods ; 12(9)2023 Apr 28.
Artículo en Inglés | MEDLINE | ID: mdl-37174377

RESUMEN

Vegetable oils provide lipids and nutrition and provide foods with a desirable flavor, color, and crispy texture when used to prepare fried foods. However, the oil quality is degraded at elevated temperatures, and thus must be examined frequently because of the damage to human health. In this study, sunflower, soybean, olive, and canola oils were examined, and their properties were measured periodically at different elevated temperatures. The unsaturated triglyceride in oils reacted with the environmental oxygen or water vapor significantly changes in optical absorbance, viscosity, electrical impedance, and acid value. We used defect kinetics to analyze the evolution of these oil properties at elevated temperatures. The optical absorbance, viscosity, and electrical impedance follow the second-order, first-order, and zeroth-order kinetics, respectively. The rate constants of the above kinetics satisfy the Arrhenius equation. Olive oil has the lowest rate of color center and dynamic viscosity among the four oils, with the smallest pre-exponential factor and the largest activation energy, respectively. The rate constants of acid reaction also satisfy the Arrhenius equation. The activation energies of the polar compound and acid reaction are almost the same, respectively, implying that the rate constant is controlled by a pre-exponential factor if four oils are compared. Olive oil has the largest rate constant of acid reaction among the four oils, with the lowest pre-exponential factor.

12.
Materials (Basel) ; 16(4)2023 Feb 07.
Artículo en Inglés | MEDLINE | ID: mdl-36837009

RESUMEN

The quality of bitumen is standardized by conventional tests. With the development of new techniques, rotational and oscillatory measuring systems are applied to evaluate bitumen under defined geometric, temperature, frequency, stress, and strain conditions that correspond to loads during asphalt production and service. Several studies have focused on determining the effect of composition on bitumen properties at service temperatures. However, there is a lack of information related to the effect of composition on viscosity at higher temperatures, which influences production processes. The different types of bitumen, samples of 50/70, 35/50, 45/80-75, and 25/55-60 bitumen, had different viscosity values in intervals corresponding to a confidence level of 95%. The viscosity-temperature relationship in temperature range of 120 to 180 °C was observed in values of 3.87 and 3.70 for unmodified bitumen and 3.09 and 3.22 for modified bitumen. The effect of differences in SARA fractions content on the variation in viscosity using regression analysis showed the importance of asphaltenes (direct correlation) and aromates (negative correlation) contents for 50/70 bitumen with a coefficient of linear regression above 0.7. In comparison, the strong effect of saturates and asphaltenes (negative correlation) and resins was identified for 45/80-75 bitumen samples with correlation of 0.5 to 0.7.

13.
Data Brief ; 47: 108854, 2023 Apr.
Artículo en Inglés | MEDLINE | ID: mdl-36798599

RESUMEN

The present work exhibits the dynamic viscosity profile data of three distinct nanofluids, at a constant shear stress, and within a range of temperatures that include below-ambient conditions (from -10 to 20 °C). The nanofluids were as follows. Nanofluid I: 30% ethylene glycol and 70% distilled water (v/v), with graphene (0.32% in mass); Nanofluid II: 30% engine coolant NBR 13705; ASTM D-3306; ASTM D-4985) and 70% distilled water (v/v), with graphene (0.2% in mass); and Nanofluid III: 30% engine coolant and 70% distilled water (v/v), with Multi-Walled Carbon Nanotubes (MWCNT) (0.2% in mass). The present work was motivated by the scarcity of experimental data on the temperature dependence of viscosity for graphene, MWCNT, and their hybrid nanofluids, at below-ambient temperatures.

14.
Micromachines (Basel) ; 14(1)2023 Jan 11.
Artículo en Inglés | MEDLINE | ID: mdl-36677244

RESUMEN

Atmospheric particulate pollution poses a great danger to the environment and human health, and there is a strong need to develop equipment for collecting and separating particulate matter of different particle sizes to study the effects of particulate matter on human health. A virtual impactor is a particle separation device based on the principle of inertial separation which provides scientific guidance for identifying the composition characteristics of particles. Much existing virtual impactor research focuses on the design of structural dimensions with little exploration of the effect of fluid properties on performance. In this paper, a microfluidic chip with a cutoff diameter of 1.85 µm was designed based on computational fluid dynamics and numerically simulated via finite element analysis to analyze important parameters such as inlet flow rate, splitting ratio and fluid properties. By numerical simulation of the split ratio, we found that the obtained collection efficiency curves could not be combined into one characteristic curve by the Stk0.5 scaling method. We therefore propose a modified Stokes number equation for predicting the cutoff diameter at different splitting ratios. The collection efficiency curves of different fluids as microfluidic chip media were plotted, and the results show that the cut particle size was reduced from 2.5 µm to 1.85 µm after replacing conventional fluid air with CO2 formed by dry ice sublimation. This is a decrease of approximately 26%, which is superior to other existing methods for reducing the cutoff diameter.

15.
Biomed Tech (Berl) ; 68(1): 39-50, 2023 Feb 23.
Artículo en Inglés | MEDLINE | ID: mdl-36351285

RESUMEN

Microfluidic devices are becoming increasingly important in various fields of pharmacy, flow chemistry and healthcare. In the embedded microchannel, the flow rates, the dynamic viscosity of the transported liquids and the fluid dynamic properties play an important role. Various functional auxiliary components of microfluidic devices such as flow restrictors, valves and flow meters need to be characterised with liquids used in several microfluidic applications. However, calibration with water does not always reflect the behaviour of the liquids used in the different applications. Therefore, several National Metrology Institutes (NMI) have developed micro-pipe viscometers for traceable inline measurement of the dynamic viscosity of liquids used in flow applications as part of the EMPIR 18HLT08 MeDDII project. These micro-pipe viscometers allow the calibration of any flow device at different flow rates and the calibration of the dynamic viscosity of the liquid or liquid mixture used under actual flow conditions. The validation of the micro-pipe viscometers has been performed either with traceable reference oils or with different liquids typically administered in hospitals, such as saline and/or glucose solutions or even glycerol-water mixtures for higher dynamic viscosities. Furthermore, measurement results of a commercially available device and a technology demonstrator for the inline measurement of dynamic viscosity and density are presented in this paper.


Asunto(s)
Glicerol , Agua , Viscosidad , Termodinámica , Temperatura , Agua/química
16.
Heliyon ; 8(12): e11831, 2022 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-36506410

RESUMEN

Present study pays more attention to optimize the performance of the hydraulic system by selecting the accurate position of the traditional hydraulic actuators. It was used HL32 as working oil, due to its ability to withstand high temperatures (15-200) °C as well as having the best mechanical properties, since the density and viscosity are the most important factors that are extremely affected on the hydraulic system. Hence, this work examined the effect of the variation kinematic, dynamic viscosity, and the density of HL32 oil on the accurate position of conventional hydraulic actuators. The kinematic and dynamic viscosity was obtained theoretically and experimentally over a wide range of temperatures ranged (20-80) °C. It was found that the percentage error between the theoretical and experimental results ranged (21∗10-6-0.023), respectively. Whereas, the deviation of the results in the actuator stroke displacement were observed 4.8%, 6%, 6.5% and 4.8% for pressure supply of 20, 30, 40 and 50 bar separately.

17.
Heliyon ; 8(12): e11944, 2022 Dec.
Artículo en Inglés | MEDLINE | ID: mdl-36478835

RESUMEN

The science of nanofluids is still fairly new and due to this, the properties of many nanofluids are yet to be explored. Therefore, equations for precise calculations in this field are not available yet. For this reason, as a thermophysical property of an MWCNT (40%)/TiO2 (60%) hybrid nanofluid (HNF), in this research, the viscosity of HNF with 10W40 oil as the base fluid, in a temperature range of T = 5-55 °C and with solid volume fractions of SVF = 0.5-1% is studied and modelled. The viscosity of the nanofluid was examined in different conditions. Lab data were used to model dynamic viscosity of HNF using the Response Surface Methodology (RSM), and first, second, third, fourth and fifth-order models were created. An analysis of the statistical parameters concluded that with a correlation coefficient of 0.9999, the fifth-order model is the best performer. The trend of alterations in viscosity shows that an increase in temperature has great effects on viscosity, and its influence is also more important than that of changes in shear rate (SR) and SVF. Optimal viscosity was also calculated and was equal to 158.1 mPa.sec at SVF = 0.05 %, SR = 11,997 s- 1 and T = 14.97 °C.

18.
Polymers (Basel) ; 14(19)2022 Sep 26.
Artículo en Inglés | MEDLINE | ID: mdl-36235979

RESUMEN

Aqueous solution of strongly hydrophilic biopolymers is known to exhibit excellent lubrication properties in biological systems, such as the synovial fluid in human joints. Several mechanisms have been proposed on the biolubrication of joints, such as the boundary lubrication and the fluid exudation lubrication. In these models, mechanical properties of synovial fluid containing biopolymers are essential. To examine the role of such biopolymers in lubrication, a series of molecular dynamics simulations with an all-atom classical force field model were conducted for aqueous solutions of hyaluronan (hyaluronic acid, HA) under constant shear. After equilibrating the system, the Lees-Edwards boundary condition was imposed, with which a steady state of uniform shear flow was realized. Comparison of HA systems with hydrocarbon (pentadecane, PD) solutions of similar mass concentration indicates that the viscosity of HA solutions is slightly larger in general than that of PDs, due to the strong hydration of HA molecules. Effects of added electrolyte (NaCl) were also discussed in terms of hydration. These findings suggest the role of HA in biolubirication as a load-supporting component, with its flexible character and strong hydration structure.

19.
Food Res Int ; 161: 111807, 2022 11.
Artículo en Inglés | MEDLINE | ID: mdl-36192885

RESUMEN

The Low Field Nuclear Magnetic Resonance (LF-NMR) intelligent analysis for lipid oxidation indices of polar compound distribution, fatty acid unsaturation, and dynamic viscosity was established and compared. LF-NMR curves obtained from the multivariate approach were more suitable for the establishment of prediction models. Results proved the ability of LF-NMR for the aging evaluation of edible oil, but different prediction performance was found for various indices. The order from the good to bad prediction was: fatty acid unsaturation > polar compound > dynamic viscosity. It demonstrated the preference of LF-NMR for reporting the information of fatty acid than triglyceride in oxidized oil. Two mechanisms for the LF-NMR method were summarized and expressed by equations. Results also supported that the peak 21 in the LF-NMR curve provided unique information about polar and low-molecular-weight products rather than polymer compounds. Data were expected for a better understanding of LF-NMR signals and to accelerate its wide application in the food industry.


Asunto(s)
Ácidos Grasos , Polímeros , Espectroscopía de Resonancia Magnética/métodos , Triglicéridos , Viscosidad
20.
Micromachines (Basel) ; 13(9)2022 Sep 05.
Artículo en Inglés | MEDLINE | ID: mdl-36144100

RESUMEN

The virtual impactor, as an atmospheric particle classification chip, provides scientific guidance for identifying the characteristics of particle composition. Most of the studies related to virtual impactors focus on their size structure design, and the effect of temperature in relation to the dynamic viscosity on the cut-off diameter is rarely considered. In this paper, a new method that can reduce the cut-off particle size without increasing the pressure drop is proposed. Based on COMSOL numerical simulations, a new ultra-low temperature virtual impactor with a cut-off diameter of 2.5 µm was designed. A theoretical analysis and numerical simulation of the relationship between temperature and the performance of the virtual impactor were carried out based on the relationship between temperature and dynamic viscosity. The effects of inlet flow rate (Q), major flow channel width (S), minor flow channel width (L) and split ratio (r) on the performance of the virtual impactor were analyzed. The collection efficiency curves were plotted based on the separation effect of the new virtual impactor on different particle sizes. It was found that the new ultra-low temperature approach reduced the PM2.5 cut-off diameter by 19% compared to the conventional virtual impactor, slightly better than the effect of passing in sheath gas. Meanwhile, the low temperature weakens Brownian motion of the particles, thus reducing the wall loss. In the future, this approach can be applied to nanoparticle virtual impactors to solve the problem of their large pressure drop.

SELECCIÓN DE REFERENCIAS
DETALLE DE LA BÚSQUEDA