Crystal structure and luminescence properties of the blue-green-emitting Ba9 (Lu, Y)2 Si6 O24 :Ce3+ phosphor.
Luminescence
; 32(5): 812-816, 2017 Aug.
Article
en En
| MEDLINE
| ID: mdl-28058768
ABSTRACT
Samples of the Ba9 (Lu2-x Yx )Si6 O24Ce3+ (x = 0-2) blue-green phosphors were synthesized by solid-state reactions. All the samples exhibited a rhombohedral crystal structure. As the Y3+ concentration increased, the diffraction peaks shifted to the small angle region and the lattice parameters increased due to the larger ionic radius of Y3+ (r = 0.900 Å) compared with that of Lu3+ (r = 0.861 Å). Under 400 nm excitation, samples exhibited strong blue-green emissions around 490 nm. The emission bands had a slight blue shift that resulted from weak crystal-field splitting with increasing Y3+ concentration. Luminescence intensity and quantum efficiency (QE) decreased with increasing Y3+ concentration. The internal QE decreased from 74 to 50% and the external QE decreased from 50 to 34% as x increased from 0 to 2. The thermal stability of the Lu series was better than that of the Y-series. The excitation band peak around 400 nm matched well with the emission light from the efficient near-ultraviolet (NUV) chip. These results indicate promising applications for these NUV-based white light-emitting diodes.
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Texto completo:
1
Base de datos:
MEDLINE
Asunto principal:
Sustancias Luminiscentes
Idioma:
En
Revista:
Luminescence
Asunto de la revista:
BIOFISICA
/
BIOQUIMICA
Año:
2017
Tipo del documento:
Article
País de afiliación:
China