Dual Role of Silver Moieties Coupled with Ordered Mesoporous Cobalt Oxide towards Electrocatalytic Oxygen Evolution Reaction.
Angew Chem Int Ed Engl
; 59(38): 16544-16552, 2020 Sep 14.
Article
en En
| MEDLINE
| ID: mdl-32537829
ABSTRACT
Herein, we show that the performance of mesostructured cobalt oxide electrocatalyst for oxygen evolution reaction (OER) can be significantly enhanced by coupling of silver species. Various analysis techniques including pair distribution function and Rietveld refinement, X-ray absorption spectroscopy at synchrotron as well as advanced electron microscopy revealed that silver exists as metallic Ag particles and well-dispersed Ag2 O nanoclusters within the mesostructure. The benefits of this synergy are twofold for OER highly conductive metallic Ag improves the charge transfer ability of the electrocatalysts while ultra-small Ag2 O clusters provide the centers that can uptake Fe impurities from KOH electrolyte and boost the catalytic efficiency of Co-Ag oxides. The current density of mesostructured Co3 O4 at 1.7â
VRHE is increased from 102 to 211â
mA cm-2 with incorporation of silver spices. This work presents the dual role of silver moieties and demonstrates a simple method to increase the OER activity of Co3 O4 .
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MEDLINE
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En
Revista:
Angew Chem Int Ed Engl
Año:
2020
Tipo del documento:
Article
País de afiliación:
Alemania