Light-induced switching of polymer-surfactant interactions enables controlled polymer thermoresponsive behaviour.
Chem Commun (Camb)
; 57(47): 5826-5829, 2021 Jun 10.
Article
en En
| MEDLINE
| ID: mdl-34002193
ABSTRACT
Hydroxypropyl cellulose (HPC) and arylazopyrazole (AAP) mixtures can be remotely controlled by light and temperature. We show that the hydrophobic interactions between HPC polymers with AAP surfactants can be drastically changed by changing the surfactants configuration through E/Z photo-isomerization. E-AAP interacts strongly with HPC which causes a dramatic increase of the critical temperature Tc of the polymers' phase transition and a loss of the coil-to-globule transition, while the hydrophobic interactions of HPC with Z-AAP are drastically reduced. As a result, E/Z photo-isomerization of AAP in mixtures with HPC offers remote control of the polymers phase transition, size and solution viscosity in an unprecedented way, and allows for new directions in colloid science.
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Base de datos:
MEDLINE
Idioma:
En
Revista:
Chem Commun (Camb)
Asunto de la revista:
QUIMICA
Año:
2021
Tipo del documento:
Article
País de afiliación:
Alemania