Emerging Ferroelectric Uniaxial Lamellar (Smectic AF) Fluids for Bistable In-Plane Polarization Memory.
J Phys Chem Lett
; 13(42): 9983-9990, 2022 Oct 27.
Article
en En
| MEDLINE
| ID: mdl-36263973
ABSTRACT
The emerging matter category of liquid-matter ferroelectrics, i.e., ferroelectric nematics, demonstrates an unprecedented combination of fluidity and spontaneous polarization. However, unlike traditional ferroelectrics, the field-switched polarization at zero-field cannot be conserved, so the memory effect remains challenging. Here we report another new type of ferroelectric liquid crystal state, dubbed the ferroelectric smectic A phase, where the polarization is longitudinally coupled to the smectic quasi-layer order. With higher packing density, the phase exhibits higher values of refractive anisotropy and spontaneous polarization compared to the ferroelectric nematics. A delicate balance between the liquid crystal elasticity and flow viscosity enables both the switching and memory of the polarization field, thus opening the door toward realizing liquid-matter ferroelectric memory devices.
Texto completo:
1
Base de datos:
MEDLINE
Idioma:
En
Revista:
J Phys Chem Lett
Año:
2022
Tipo del documento:
Article
País de afiliación:
China