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Slow Magnetic Relaxation and Modulated Photoluminescent Emission of Coordination Polymer Based on 3-Amino-4-hydroxybenzoate Zn and Co Metal Ions.
Echenique-Errandonea, Estitxu; Rojas, Sara; Cepeda, Javier; Choquesillo-Lazarte, Duane; Rodríguez-Diéguez, Antonio; Seco, José M.
Afiliación
  • Echenique-Errandonea E; Applied Chemistry Department, Faculty of Chemistry, University of the Basque Country (UPV/EHU), Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, Spain.
  • Rojas S; Inorganic Chemistry Department, Faculty of Sciences, University of Granada, Avda. Fuentenueva S/N, 18002 Granada, Spain.
  • Cepeda J; Applied Chemistry Department, Faculty of Chemistry, University of the Basque Country (UPV/EHU), Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, Spain.
  • Choquesillo-Lazarte D; Laboratory for Crystallographic Studies IACT, CSIC-UGR, Av. Las Palmeras n°4, 18100 Granada, Spain.
  • Rodríguez-Diéguez A; Inorganic Chemistry Department, Faculty of Sciences, University of Granada, Avda. Fuentenueva S/N, 18002 Granada, Spain.
  • Seco JM; Applied Chemistry Department, Faculty of Chemistry, University of the Basque Country (UPV/EHU), Paseo Manuel de Lardizabal 3, 20018 Donostia-San Sebastián, Spain.
Molecules ; 28(4)2023 Feb 15.
Article en En | MEDLINE | ID: mdl-36838833
ABSTRACT
As a starting point, a new 3D porous framework with the {[CoL]·0.5DMF·H2O}n chemical formula (where L = 3-amino-4-hydroxybenzoate) is described. Its performance as a single molecule magnet was explored. The study of magnetic properties reveals that Co-MOF shows no frequency-fdependant alternating current (ac) signals under zero direct current (dc) magnetic field, whereas single-molecule magnet behaviour is achieved when CoII ions are diluted in a ZnII based matrix. Interestingly, this strategy renders a bifunctional [CoxZn1-xL]n material that is also characterized by a strong photoluminescent emitting capacity.
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Texto completo: 1 Base de datos: MEDLINE Asunto principal: Polímeros / Metales Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2023 Tipo del documento: Article País de afiliación: España
Texto completo
Imprimir
XML
PubMed Links
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Texto completo: 1 Base de datos: MEDLINE Asunto principal: Polímeros / Metales Idioma: En Revista: Molecules Asunto de la revista: BIOLOGIA Año: 2023 Tipo del documento: Article País de afiliación: España