Graphene oxide/cellulose nanofibril composite: A high-performance catalyst for the fabrication of an electrochemical sensor for quantification of p-nitrophenol, a hazardous water pollutant.

ABSTRACT

The detection and quantification of p-Nitrophenol in environmental samples are important for understanding the extent and impact of environmental pollution, protecting human health, ensuring regulatory compliance, and guiding remediation efforts. The main objective of this work was to investigate the electrochemical performance of a graphene oxide/cellulose nanofibril composite (GO/CNF) modified carbon paste electrode (GO/CNF/CPE) for the sensitive and reliable detection of p-nitrophenol in water samples. The transmission electron microscopy (TEM) technique was employed to enlighten the structure of nanocomposites. The electrochemical behavior of the fabricated electrochemical sensor was characterized via differential pulse voltammetry (DPV), linear sweep voltammetry (LSV), and electrochemical impedance spectroscopy (EIS). Under optimized analytical conditions, the peak current of the analyte showed a wide linear relationship with its concentration in a range of 3.0 nM-210 µM with a low amount of the limit of detection (LOD) value of 0.8 nM determined by the DPV method. The proposed electrochemical sensor demonstrated excellent sensitivity, selectivity, and accuracy metrics in real sample analysis of p-nitrophenol.