Integration of a Bismuth-Based Tris-Mononuclear Complex with 2D Functional Materials for Highly Efficient and Durable Aqueous Electrocatalytic Hydrogen Evolution.

ABSTRACT

The eminence of transitioning from traditional fossil fuel-based energy resources to renewable and sustainable energy sources is most evidently crucial. The potential of hydrogen as an alternative energy source has specifically focuses the electrocatalytic water splitting (EWS) as a promising technique for generating hydrogen. Development of efficient electrocatalysts to facilitate the EWS process while rationalizing the limitations of noble metal catalysts like platinum has become one of the daunting tasks. Consequently, porous functional materials such as metal complexes (MCs) and graphene oxide (GO) can act as potential catalysts for EWS. Therefore, a composite of GO and a mononuclear bismuth metal complex is synthesized through in situ facile synthesis, which is further utilized as an efficient electrocatalyst for the hydrogen evolution reaction (HER). Several potential electrocatalytic MC@GO composite (BMGO-3,5,7) materials were prepared with compositional variation of GO (3, 5, and 7 wt %). The experimental results demonstrate that the BMGO5 composite exhibits excellent HER activity with a low overpotential value of 105 mV at 10 mA cm-2 and a low Tafel slope of 44 mV dec-1 in 1 M KOH solution. Furthermore, a comprehensive investigation on the potentiality of the BMC-GO composite for hydrogen evolution from river water splitting was performed in order to address the issue of freshwater depletion. Inclusion of a mononuclear MC for facile synthesis of functional GO-based efficient electrocatalyst material is very scanty in the literature. This unique approach could assist future research endeavors toward designing efficient electrocatalysts for sustainable renewable energy generation. This is one of the first of its kind, where mononuclear MCs were utilized to develop GO-based functional composite materials for efficient electrocatalysis toward sustainable renewable energy generation.