Synthesis of [60]Fullerene-Fused Lactones via Carboxylic Acid Group-Directed C-H Bond Activation and Further Retro Baeyer-Villiger Reaction.
Org Lett
; 26(25): 5300-5305, 2024 Jun 28.
Article
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| MEDLINE
| ID: mdl-38885445
ABSTRACT
An efficient palladium-catalyzed reaction of [60]fullerene with benzoic acids via carboxylic acid group-directed C-H bond activation is achieved. The obtained [60]fullerene-fused lactones can undergo a retro Baeyer-Villiger reaction to provide [60]fullerene-fused ketones via apparent reduction in the presence of triflic acid. A representative ketone product obtained by the reduction reaction can be employed as an overcoating layer for the electron-transporting layer in an n-type perovskite solar cell.
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MEDLINE
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En
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Org Lett
Asunto de la revista:
BIOQUIMICA
Año:
2024
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Article