Designer phospholipid capping ligands for soft metal halide nanocrystals.

The success of colloidal semiconductor nanocrystals (NCs) in science and optoelectronics is inextricable from their surfaces. The functionalization of lead halide perovskite NCs1-5 poses a formidable challenge because of their structural lability, unlike the well-established covalent ligand capping of conventional semiconductor NCs6,7. We posited that the vast and facile molecular engineering of phospholipids as zwitterionic surfactants can deliver highly customized surface chemistries for metal halide NCs. Molecular dynamics simulations implied that ligand-NC surface affinity is primarily governed by the structure of the zwitterionic head group, particularly by the geometric fitness of the anionic and cationic moieties into the surface lattice sites, as corroborated by the nuclear magnetic resonance and Fourier-transform infrared spectroscopy data. Lattice-matched primary-ammonium phospholipids enhance the structural and colloidal integrity of hybrid organic-inorganic lead halide perovskites (FAPbBr3 and MAPbBr3 (FA, formamidinium; MA, methylammonium)) and lead-free metal halide NCs. The molecular structure of the organic ligand tail governs the long-term colloidal stability and compatibility with solvents of diverse polarity, from hydrocarbons to acetone and alcohols. These NCs exhibit photoluminescence quantum yield of more than 96% in solution and solids and minimal photoluminescence intermittency at the single particle level with an average ON fraction as high as 94%, as well as bright and high-purity (about 95%) single-photon emission.

A prototype system for the hydrothermal oxidation of feces.

To ensure access to safe sanitation facilities in rural communities, cheap off-grid technologies need to be developed to substitute pit latrines and open defecation. In this study, we present a prototype system based on hydrothermal oxidation, which, under optimal conditions, converts a fecal sludge simulant almost completely to CO 2 and water, leaving behind only a carbon-poor aqueous phase with the minerals. The prototype has been designed to process the feces from two households. This technology does not only enable a fast and complete conversion, but is potentially also very energy efficient, as the feed does not require any pre-treatment or drying. The system was found to effectively remove 97-99% of the total organic carbon within a reaction time of 600 s under an external energy demand of roughly 4 kWh per kilogram of wet feces by using the oxygen in air as an oxidant. A total of ten experiments with varying injection pressure, total solids content of the feed, and residence time in the reactor were performed to find experimental settings with high conversion. Only when the residence time was decreased from 600 to 300 s did the conversion fall significantly below 97%. To reach a target value of 99.9% TOC conversion, the reactor temperature and/or the residence time must be increased further. To achieve a system applicable in regions with no connection to the energy grid, the thermal loss of the reactor insulation needs to be lowered further to achieve an overall thermally self-sustaining operation.