Mesoporous carbon material prepared from sewage sludge hydrochar using Pluronic F127 as template for efficient removal of phenolic compounds: Experimental study and mechanism interpretation via advanced statistical physics model.

Mesoporous carbon material (MCM) with rich ether surface group was prepared from sewage sludge hydrochar using Pluronic F127 as template under pyrolysis activation, which provided an energy-efficient method to promote the resource utilization of sewage sludge as adsorbents for phenols removal from water. The MCM possessed high surface area (549 m2/g), abundant mesopores (average width 3.81 nm) and well-developed graphite structure. Acidic conditions and low temperatures favored the adsorption of phenolic compounds. The quick adsorption process of reaching over 85% of the capacity in the first 10 min and intraparticle diffusion as primary rate-limiting step were observed for all phenolic compounds. Advanced statistical physics analysis was used successfully to interpret the adsorption mechanism of phenols onto MCM and revealed a multi-molecular monolayer adsorption process primarily through negative charge-assisted hydrogen bond interaction where the ether functional group contributed to the predominant active sites. The adsorption capacity of phenolic compounds depended upon the number of molecules adsorbed per ether active site and the available density of ether bond group on the surface of MCM. 2,4,6-trichlorophenol showed a highest adsorption priority to occupy the limited ether active sites and its adsorption capacity reached 0.49 mmol/g, while p-nitrophenol exhibited a maximum number of molecules adsorbed on the single ether active site, showing an adsorption capacity of 0.42 mmol/g. The synergistic effect of multi-interactions mechanisms resulted in phenolic compounds removal with adsorption energies lower than 30 kJ/mol. This prepared MCM adsorbent is promising for application in treatment of water polluted by phenols.

Application of life cycle assessment for municipal solid waste management options in Hohhot, People's Republic of China.

With increasing population and urbanization levels in the People's Republic of China, environmental problems related to the management of municipal solid waste (MSW) are inevitable. This study aimed to determine the environmental impact of the current MSW management system in Hohhot City and to establish an optimum future strategy for it by applying life cycle assessment (LCA) methodology. Four scenarios were compared using the CML-IA impact characterization method, which took into account their potential contribution to global warming, ozone depletion, human toxicity, photochemical ozone creation, acidification, and eutrophication potentials. The system boundaries included the collection and recycling, transfer and transportation of MSW, and its disposal by incineration, landfilling, and carbon dioxide (CO2) capture methods. The results showed that the scenario involving landfill and incineration in a ratio of 1:5 was the optimal waste management option; however, increasing the proportion of waste incinerated led to a significant increase in global warming potential. Additional technologies are thus required to overcome this problem, and it was found that the use of CO2 capture technology resulted in a 30% reduction in the total environmental impact potential. This study's results indicate that LCA is a valuable and practical tool to support decision-making that can be used to suggest problematic areas in current waste management strategies and to determine an optimal alternative to the solid waste management option.

Carbon-rich and low-ash hydrochar formation from sewage sludge by alkali-thermal hydrolysis coupled with acid-assisted hydrothermal carbonization.

The production of carbon-rich and low-ash hydrochar from sewage sludge is attracting interest due to its great application prospect in high value-added carbon materials fields, but which is impossible through direct hydrothermal carbonization. In this study, alkali-thermal hydrolysis followed by acid-assisted hydrothermal carbonization was thus proposed. Thermal hydrolysis at strong alkaline environment was more effective than acid one to promote the dissolution of organic matters and restrain the release of inorganic matters from sludge, which created a favorable condition for hydrochar formation in a carbon-rich and low-ash way. Alkali-thermal hydrolysis began to show a positive effect on the dissolution of organics in sludge when temperature exceeded the threshold of 90 °C, and an increase of 9.77 % was found at 150 °C when compared to 30 °C. Acid-assisted hydrothermal carbonization of alkali-thermal hydrolysate (ATH) at pH 1.0 strongly promoted condensation polymerization of dissolved organics to form hydrochar and meanwhile inhibited introduction of dissolved inorganics. The nanosized microparticulate hydrochar derived from ATH-30 had a carbon and ash content of 50.98-61.31 % and 10.76-12.09 %, while the micro-sized microspheric hydrochar with multiple deposition layers formed from ATH-150 showed a better performance in carbon-rich and low-ash aspect where a carbon and ash content of 58.24-70.07 % and 0.40-3.24 % was realized, both of which were obviously superior to the direct hydrochar (carbon 34.86 % and ash 46.11 %). The condensation of dissolved organics during alkali-thermal hydrolysis stage is important to the carbonization degree of hydrochar. This study provides a new perspective in sludge disposal and production of advanced carbon materials.

Relationship between enhanced dewaterability and structural properties of hydrothermal sludge after hydrothermal treatment of excess sludge.

Hydrothermal treatment is an effective method to enhance the deep dewaterability of excess sludge with low energy consumption. In this study, an insight into the relationship between enhanced dewaterability and structural properties of the produced hydrothermal sludge was presented, aiming at better understanding the effect of hydrothermal process on excess sludge dewatering performance. The results indicated that hydrothermal effect induced the transformation of surface water to interstitial and free water by lowering the binding strength between adjacent water and solid particles and that free water became the main form for moisture existence in hydrothermal sludge as temperature was higher than 180 °C. Increase in temperature of hydrothermal treatment generated a significant size reduction of sludge flocs but treated sludge with a higher rigidity, which not only strengthened the network of hydrothermal sludge but also destroyed the binding of EPS with water. Hydrothermal process caused crevice and pore structures of excess sludge to disappear gradually, which was a main driving force of water removal as temperature was below 150 °C. With the temperature of hydrothermal treatment exceeding 180 °C, the morphology of hydrothermal sludge became rough which linked closely to the solid precipitation of condensation polymerization, and further became smooth at higher temperature (210 °C) due to the coal-like structures with higher aromaticities, indicating that hydrothermal reaction pathways began to play a main role in enhanced dewaterability. Hydrothermal treatment led to more alkyl and aromatic carbon, but lower O-alkyl, carboxyl and carbonyl carbon.